In:
RSC Advances, Royal Society of Chemistry (RSC), Vol. 11, No. 45 ( 2021), p. 27860-27867
Abstract:
Biomass-derived carbon materials have been widely researched due to their advantages such as low cost, environmental friendliness, readily available raw materials. Black fungus and Hericium erinaceus contain many kinds of amino acids. In this paper, unique O, N-codoped black fungus-derived activated carbons (FAC X ), and Hericium erinaceus -derived activated carbons (HAC X ) were prepared by KOH chemical activation under different temperatures without adding additional reagents containing nitrogen and oxygen functional groups, respectively. As electrode materials of symmetric supercapacitors, FAC 2 and HAC 2 calcined at 800 °C exhibited the highest specific capacitance of 209.3 F g −1 and 238.6 F g −1 at 1.0 A g −1 in the two-electrode configuration with 6.0 M KOH as the electrolyte, respectively. The X-ray photoelectron spectroscopy confirmed that the as-synthesized FAC X and HAC X contained small amounts of nitrogen and oxygen elements. Moreover, heteroatom-doped FAC 2 and HAC 2 electrode materials shown excellent rate performance (84.1% and 75.0% capacitance retention at 20 A g −1 , respectively). By comparison, the oxygen-rich hierarchical porous carbon (HAC 2 ) shows higher specific capacitance and energy density and longer cycling performance. Nevertheless, carbon-rich hierarchical porous carbon (FAC 2 ) indicates excellent rate performance. Biomass-derived heteroatom self-doped porous carbons are expected to become ideal active materials for high performance supercapacitor.
Type of Medium:
Online Resource
ISSN:
2046-2069
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2021
detail.hit.zdb_id:
2623224-8
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