In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 643, No. 2 ( 2017-01), p. 214-219
Abstract:
The metal‐organic frameworks (MOFs), {[Cd(L)(H 2 O)] · CH 3 OH · DMF} ( 1 ) and [Pb(L)(DMF)] ( 2 ) (L = 2,4‐dihydroxybenzaldehyde nicotinoylhydrazone), were synthesized and characterized using microanalyses, IR spectroscopy, and single‐crystal X‐ray diffraction. Single crystal X‐ray analyses revealed that both 1 and 2 exhibit 2D grid networks. The photoluminescence investigation indicates that 1 and 2 could be a prospective candidate for developing luminescencent sensors for the selective sensing of nitrobenzene, which is used as a precursor for explosives. The luminescent properties of 1 and 2 in different solvents were investigated and corroborated by theoretical calculations. Additionally compounds 1 and 2 also show selective sensing ability for Fe 3+ as well as for CrO 4 2– ions.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.201600344
Language:
English
Publisher:
Wiley
Publication Date:
2017
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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