In:
Chemistry Letters, Oxford University Press (OUP), Vol. 33, No. 3 ( 2004-03-01), p. 350-351
Abstract:
A tripodal hexadentate ligand containing three imidazole groups gives spin-crossover iron complexes in both the +II and the +III oxidation states. The tetrafluoroborate salt of the Fe(II) complex shows a gradual spin transition in the temperature range 110–270 K. The corresponding Fe(III) complex shows a spin transition above 150 K, and at 300 K ca. 87% of the Fe(III) ion is in the high-spin state.
Type of Medium:
Online Resource
ISSN:
0366-7022
,
1348-0715
Language:
English
Publisher:
Oxford University Press (OUP)
Publication Date:
2004
detail.hit.zdb_id:
2063626-X
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