In:
Chemistry – An Asian Journal, Wiley, Vol. 12, No. 6 ( 2017-03-16), p. 648-654
Abstract:
Herein, 9,10‐dihydro‐9,9‐dimethylacridine (Ac) or phenoxazine (PXZ)‐substituted isonicotinonitrile (INN) derivatives, denoted as 2AcINN , 26AcINN , and 26PXZINN , were developed as a series of thermally activated delayed fluorescence (TADF) emitters. These emitters showed reasonably high photoluminescence quantum yields of 71–79 % in the host films and high power efficiency organic light‐emitting diodes (OLEDs). Sky‐blue emitter 26AcINN exhibited a low turn‐on voltage of 2.9 V, a high external quantum efficiency ( η ext ) of 22 %, and a high power efficiency ( η p ) of 66 lm W −1 with Commission Internationale de l′Eclairage (CIE) chromaticity coordinates of (0.22, 0.45), whereas green emitter 26PXZINN exhibited a low turn‐on voltage of 2.2 V, a high η ext of 22 %, and a high η p of 99 lm W −1 with CIE chromaticity coordinates of (0.37, 0.58). These performances are among the best for TADF OLEDs to date.
Type of Medium:
Online Resource
ISSN:
1861-4728
,
1861-471X
DOI:
10.1002/asia.201601641
Language:
English
Publisher:
Wiley
Publication Date:
2017
detail.hit.zdb_id:
2233006-9
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