In:
Angewandte Chemie, Wiley, Vol. 131, No. 7 ( 2019-02-11), p. 2062-2066
Abstract:
In the design of machinery such as steel bearings, a fundamental understanding of material characteristics provides an indispensable basis for the design. Although hydrocarbon cycloarylenes have started to be used for providing unique supramolecular bearings with anomalous dynamic behaviors, their fundamental understanding is immature. A unique property of the cycloarylene host is now reported: the cyclic host is so pliable that it tracks the orientational changes of the ellipsoidal guest, that is, C 70 fullerene. Unique structures of the complex were revealed by spectroscopic and crystallographic analyses, and additional theoretical investigations deepened our understanding by revealing the structural changes associated with unbiased rotational motions.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.201812771
Language:
English
Publisher:
Wiley
Publication Date:
2019
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505868-5
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506609-8
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514305-6
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505872-7
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1479266-7
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505867-3
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506259-7
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