In:
Angewandte Chemie, Wiley, Vol. 130, No. 17 ( 2018-04-16), p. 4684-4688
Abstract:
Herein, an efficient route to enantioenriched organosilanes, containing two consecutive stereogenic centers, from enals and β‐silyl enones under carbene organocatalysis is described. Under mild reaction conditions, this transition‐metal‐free strategy exhibits a broad substrate scope, and excellent diastereo‐ and enantioselectivity.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v130.17
DOI:
10.1002/ange.201800483
Language:
English
Publisher:
Wiley
Publication Date:
2018
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505872-7
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1479266-7
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