In:
Angewandte Chemie, Wiley, Vol. 131, No. 45 ( 2019-11-04), p. 16298-16301
Abstract:
An S‐shaped gas isotherm pattern displays high working capacity in pressure‐swing adsorption cycle, as established for CO 2 , CH 4 , acetylene, and CO. However, to our knowledge, this type of adsorption behavior has not been revealed for NH 3 gas. Herein, we design and characterize a hydrogen‐bonded organic framework (HOF) that can adsorb NH 3 uniquely in an S‐shape (type IV) fashion. While conventional porous materials, mostly with type I NH 3 adsorption behavior, require relatively high regeneration temperature, this platform which has significant working capacity is easily regenerated and recyclable at room temperature.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v131.45
DOI:
10.1002/ange.201911087
Language:
English
Publisher:
Wiley
Publication Date:
2019
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505868-5
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506609-8
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514305-6
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505872-7
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1479266-7
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505867-3
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506259-7
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