In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2018, No. 15 ( 2018-04-23), p. 1679-1682
Abstract:
The isolation of binary As–N and ternary As–N–P cage compounds consisting exclusively of group 15 elements was achieved by exploiting the reactivity of diarsadiazanediyl. This arsenic centered biradical is capable of activating and/or quenching small molecules bearing double bonds such as diazenes, Ph–N=N–Ph, or in situ generated labile diphosphenes, e.g. Ph–P=P–Ph, leading to the formation of hexapnicta‐[2.1.1]bicyclohexanes.
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2018.15
DOI:
10.1002/ejic.201800109
Language:
English
Publisher:
Wiley
Publication Date:
2018
detail.hit.zdb_id:
1475009-0
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