In:
Advanced Synthesis & Catalysis, Wiley, Vol. 359, No. 22 ( 2017-11-23), p. 3900-3904
Abstract:
The rhodium(III)‐catalyzed cross‐coupling reaction between N ‐sulfonyl aldimines and various olefins such as maleimides, fumarates, maleates, α,β‐unsaturated ketones, acrylate and nitroalkenes is described. This transformation efficiently leads to the diastereoselective synthesis of pharmacologically privileged 1‐aminoindane derivatives via the C−H alkylation followed by subsequent intramolecular cyclization. Notably, single diastereomers in all cases were observed, and the relative stereochemistry of products was confirmed by the X‐ray crystallographic data. magnified image
Type of Medium:
Online Resource
ISSN:
1615-4150
,
1615-4169
DOI:
10.1002/adsc.v359.22
DOI:
10.1002/adsc.201701082
Language:
English
Publisher:
Wiley
Publication Date:
2017
detail.hit.zdb_id:
2041384-1
detail.hit.zdb_id:
2033084-4
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