In:
Angewandte Chemie, Wiley, Vol. 128, No. 28 ( 2016-07-04), p. 8150-8154
Abstract:
One‐dimensional (1D) transition metal oxide (TMO) nanostructures are actively pursued in spintronic devices owing to their nontrivial d electron magnetism and confined electron transport pathways. However, for TMOs, the realization of 1D structures with long‐range magnetic order to achieve a sensitive magnetoelectric response near room temperature has been a longstanding challenge. Herein, we exploit a chemical hydric effect to regulate the spin structure of 1D V–V atomic chains in monoclinic VO 2 nanowires. Hydrogen treatment introduced V 3+ (3d 2 ) ions into the 1D zigzag V–V chains, triggering the formation of ferromagnetically coupled V 3+ –V 4+ dimers to produce 1D superparamagnetic chains and achieve large room‐temperature negative magnetoresistance (−23.9 %, 300 K, 0.5 T). This approach offers new opportunities to regulate the spin structure of 1D nanostructures to control the intrinsic magnetoelectric properties of spintronic materials.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v128.28
DOI:
10.1002/ange.201603406
Language:
English
Publisher:
Wiley
Publication Date:
2016
detail.hit.zdb_id:
505868-5
detail.hit.zdb_id:
506609-8
detail.hit.zdb_id:
514305-6
detail.hit.zdb_id:
505872-7
detail.hit.zdb_id:
1479266-7
detail.hit.zdb_id:
505867-3
detail.hit.zdb_id:
506259-7
Permalink