In:
Chemistry – A European Journal, Wiley, Vol. 9, No. 13 ( 2003-07-07), p. 2963-2968
Abstract:
The dipyridylphosphane/diamine–Ru complex combined with t BuOK in 2propanol acts as a very effective catalyst system for the enantioselective hydrogenation of a diverse range of simple ketones including heteroaromatic ketones, substituted benzophenones, alkenyl ketones, and cyclopropyl ketones. The combination of desirable features, such as quantitative chemical yields within hours, broad substrate scope, excellent enantioselectivities (up to 99 %), and high substrate‐to‐catalyst ratios, among others, makes the present catalyst system of high practical interest.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.200204688
Language:
English
Publisher:
Wiley
Publication Date:
2003
detail.hit.zdb_id:
1478547-X
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