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  • 1
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 16, No. 23 ( 2016-12-12), p. 15397-15412
    Abstract: Abstract. Deliberate injection of aerosol particles into the stratosphere is a potential climate engineering scheme. Particles injected into the stratosphere would scatter solar radiation back to space, thereby reducing the temperature at the Earth's surface and hence the impacts of global warming. Minerals such as TiO2 or SiO2 are among the potentially suitable aerosol materials for stratospheric particle injection due to their greater light-scattering ability than stratospheric sulfuric acid particles. However, the heterogeneous reactivity of mineral particles towards trace gases important for stratospheric chemistry largely remains unknown, precluding reliable assessment of their impacts on stratospheric ozone, which is of key environmental significance. In this work we have investigated for the first time the heterogeneous hydrolysis of ClONO2 on TiO2 and SiO2 aerosol particles at room temperature and at different relative humidities (RHs), using an aerosol flow tube. The uptake coefficient, γ(ClONO2), on TiO2 was ∼ 1.2 × 10−3 at 7 % RH and remained unchanged at 33 % RH, and increased for SiO2 from ∼ 2 × 10−4 at 7 % RH to  ∼ 5 × 10−4 at 35 % RH, reaching a value of  ∼ 6 × 10−4 at 59 % RH. We have also examined the impacts of a hypothetical TiO2 injection on stratospheric chemistry using the UKCA (United Kingdom Chemistry and Aerosol) chemistry–climate model, in which heterogeneous hydrolysis of N2O5 and ClONO2 on TiO2 particles is considered. A TiO2 injection scenario with a solar-radiation scattering effect very similar to the eruption of Mt Pinatubo was constructed. It is found that, compared to the eruption of Mt Pinatubo, TiO2 injection causes less ClOx activation and less ozone destruction in the lowermost stratosphere, while reduced depletion of N2O5 and NOx in the middle stratosphere results in decreased ozone levels. Overall, no significant difference in the vertically integrated ozone abundances is found between TiO2 injection and the eruption of Mt Pinatubo. Future work required to further assess the impacts of TiO2 injection on stratospheric chemistry is also discussed.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2016
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    detail.hit.zdb_id: 2069847-1
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  • 2
    Online Resource
    Online Resource
    Proceedings of the National Academy of Sciences ; 2020
    In:  Proceedings of the National Academy of Sciences Vol. 117, No. 43 ( 2020-10-27), p. 26651-26659
    In: Proceedings of the National Academy of Sciences, Proceedings of the National Academy of Sciences, Vol. 117, No. 43 ( 2020-10-27), p. 26651-26659
    Abstract: The 1257 CE eruption of Mount Samalas (Indonesia) is the source of the largest stratospheric injection of volcanic gases in the Common Era. Sulfur dioxide emissions produced sulfate aerosols that cooled Earth’s climate with a range of impacts on society. The coemission of halogenated species has also been speculated to have led to wide-scale ozone depletion. Here we present simulations from HadGEM3-ES, a fully coupled Earth system model, with interactive atmospheric chemistry and a microphysical treatment of sulfate aerosol, used to assess the chemical and climate impacts from the injection of sulfur and halogen species into the stratosphere as a result of the Mt. Samalas eruption. While our model simulations support a surface air temperature response to the eruption of the order of −1°C, performing well against multiple reconstructions of surface temperature from tree-ring records, we find little evidence to support significant injections of halogens into the stratosphere. Including modest fractions of the halogen emissions reported from Mt. Samalas leads to significant impacts on the composition of the atmosphere and on surface temperature. As little as 20% of the halogen inventory from Mt. Samalas reaching the stratosphere would result in catastrophic ozone depletion, extending the surface cooling caused by the eruption. However, based on available proxy records of surface temperature changes, our model results support only very minor fractions (1%) of the halogen inventory reaching the stratosphere and suggest that further constraints are needed to fully resolve the issue.
    Type of Medium: Online Resource
    ISSN: 0027-8424 , 1091-6490
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    Language: English
    Publisher: Proceedings of the National Academy of Sciences
    Publication Date: 2020
    detail.hit.zdb_id: 209104-5
    detail.hit.zdb_id: 1461794-8
    SSG: 11
    SSG: 12
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  • 3
    In: Earth's Future, American Geophysical Union (AGU), Vol. 10, No. 8 ( 2022-08)
    Abstract: Future changes in Near Term Climate Forcers have important implications for both air quality and climate Combined mitigation of aerosols and methane is required to achieve maximum co‐benefits to both future air quality and climate Future changes in land‐use and climate also impact the level of mitigation required to anthropogenic sources of near‐term climate forcers
    Type of Medium: Online Resource
    ISSN: 2328-4277 , 2328-4277
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2022
    detail.hit.zdb_id: 2746403-9
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  • 4
    In: Journal of Advances in Modeling Earth Systems, American Geophysical Union (AGU), Vol. 12, No. 9 ( 2020-09)
    Abstract: UKESM1 performs well across a range of variables and components of the North Atlantic climate system when compared with observations A range of shortcomings are still present in the simulations, however, with many shortcomings similar to those of the physical climate model Development of the physical model, alongside the Earth system components, is crucial for improved climate simulations
    Type of Medium: Online Resource
    ISSN: 1942-2466 , 1942-2466
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2020
    detail.hit.zdb_id: 2462132-8
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  • 5
    In: Geoscientific Model Development, Copernicus GmbH, Vol. 16, No. 15 ( 2023-08-03), p. 4451-4479
    Abstract: Abstract. Changes in anthropogenic aerosol emissions have strongly contributed to global and regional trends in temperature, precipitation, and other climate characteristics and have been one of the dominant drivers of decadal trends in Asian and African precipitation. These and other influences on regional climate from changes in aerosol emissions are expected to continue and potentially strengthen in the coming decades. However, a combination of large uncertainties in emission pathways, radiative forcing, and the dynamical response to forcing makes anthropogenic aerosol a key factor in the spread of near-term climate projections, particularly on regional scales, and therefore an important one to constrain. For example, in terms of future emission pathways, the uncertainty in future global aerosol and precursor gas emissions by 2050 is as large as the total increase in emissions since 1850. In terms of aerosol effective radiative forcing, which remains the largest source of uncertainty in future climate change projections, CMIP6 models span a factor of 5, from −0.3 to −1.5 W m−2. Both of these sources of uncertainty are exacerbated on regional scales. The Regional Aerosol Model Intercomparison Project (RAMIP) will deliver experiments designed to quantify the role of regional aerosol emissions changes in near-term projections. This is unlike any prior MIP, where the focus has been on changes in global emissions and/or very idealised aerosol experiments. Perturbing regional emissions makes RAMIP novel from a scientific standpoint and links the intended analyses more directly to mitigation and adaptation policy issues. From a science perspective, there is limited information on how realistic regional aerosol emissions impact local as well as remote climate conditions. Here, RAMIP will enable an evaluation of the full range of potential influences of realistic and regionally varied aerosol emission changes on near-future climate. From the policy perspective, RAMIP addresses the burning question of how local and remote decisions affecting emissions of aerosols influence climate change in any given region. Here, RAMIP will provide the information needed to make direct links between regional climate policies and regional climate change. RAMIP experiments are designed to explore sensitivities to aerosol type and location and provide improved constraints on uncertainties driven by aerosol radiative forcing and the dynamical response to aerosol changes. The core experiments will assess the effects of differences in future global and regional (Africa and the Middle East, East Asia, North America and Europe, and South Asia) aerosol emission trajectories through 2051, while optional experiments will test the nonlinear effects of varying emission locations and aerosol types along this future trajectory. All experiments are based on the shared socioeconomic pathways and are intended to be performed with 6th Climate Model Intercomparison Project (CMIP6) generation models, initialised from the CMIP6 historical experiments, to facilitate comparisons with existing projections. Requested outputs will enable the analysis of the role of aerosol in near-future changes in, for example, temperature and precipitation means and extremes, storms, and air quality.
    Type of Medium: Online Resource
    ISSN: 1991-9603
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2023
    detail.hit.zdb_id: 2456725-5
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  • 6
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 2022
    In:  Nature Vol. 608, No. 7924 ( 2022-08-25), p. 719-723
    In: Nature, Springer Science and Business Media LLC, Vol. 608, No. 7924 ( 2022-08-25), p. 719-723
    Type of Medium: Online Resource
    ISSN: 0028-0836 , 1476-4687
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    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2022
    detail.hit.zdb_id: 120714-3
    detail.hit.zdb_id: 1413423-8
    SSG: 11
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  • 7
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 127, No. 16 ( 2022-08-27)
    Abstract: New multi‐model results show significant positive effects of ozone precursors on near‐global ozone offsetting the negative effects of ozone‐depleting substances (ODSs) ODS and greenhouse gases dominate stratospheric ozone changes but with large inter‐model differences due to uncertainties in responses to ODS changes Increases in carbon dioxide and nitrous oxide significantly impact stratospheric ozone, but their net effects on total columns are small due to cancellations
    Type of Medium: Online Resource
    ISSN: 2169-897X , 2169-8996
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2022
    detail.hit.zdb_id: 710256-2
    detail.hit.zdb_id: 2016800-7
    detail.hit.zdb_id: 2969341-X
    SSG: 16,13
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  • 8
    In: Journal of Advances in Modeling Earth Systems, American Geophysical Union (AGU), Vol. 11, No. 12 ( 2019-12), p. 4513-4558
    Abstract: UKESM1 represents a major advance over its predecessor HadGEM2‐ES, both in the complexity of its components and its internal coupling The complex coupling presents challenges to the model development; we document the tuning process employed to obtain acceptable performance UKESM1 performs well, having a stable pre‐industrial state and showing good agreement with observations in a wide variety of contexts
    Type of Medium: Online Resource
    ISSN: 1942-2466 , 1942-2466
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2019
    detail.hit.zdb_id: 2462132-8
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  • 9
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 20, No. 12 ( 2020-06-19), p. 7153-7166
    Abstract: Abstract. The temporal evolution of the abundance of long-lived, anthropogenic chlorofluorocarbons in the atmosphere is a major factor in determining the timing of total column ozone (TCO) recovery. Recent observations have shown that the atmospheric mixing ratio of CFC-11 is not declining as rapidly as expected under full compliance with the Montreal Protocol and indicate a new source of CFC-11 emissions. In this study, the impact of a number of potential future CFC-11 emissions scenarios on the timing of the TCO return to the 1960–1980 mean (an important milestone on the road to recovery) is investigated using the Met Office's Unified Model (Hewitt et al., 2011) coupled with the United Kingdom Chemistry and Aerosol scheme (UM-UKCA). Key uncertainties related to this new CFC-11 source and their impact on the timing of the TCO return date are explored, including the duration of new CFC-11 production and emissions; the impact of any newly created CFC-11 bank; and the effects of co-production of CFC-12. Scenario-independent relationships are identified between cumulative CFC emissions and the timing of the TCO return date, which can be used to establish the impact of future CFC emissions pathways on ozone recovery in the real world. It is found that, for every 200 Gg Cl (∼258 Gg CFC-11) emitted, the timing of the global TCO return to 1960–1980 averaged values is delayed by ∼0.56 years. However, a marked hemispheric asymmetry in the latitudinal impacts of cumulative Cl emissions on the timing of the TCO return date is identified, with longer delays in the Southern Hemisphere than the Northern Hemisphere for the same emission. Together, these results indicate that, if rapid action is taken to curb recently identified CFC-11 production, then no significant delay in the timing of the TCO return to the 1960–1980 mean is expected, highlighting the importance of ongoing, long-term measurement efforts to inform the accountability phase of the Montreal Protocol. However, if the emissions are allowed to continue into the future and are associated with the creation of large banks, then significant delays in the timing of the TCO return date may occur.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2020
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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  • 10
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 21, No. 5 ( 2021-03-18), p. 4187-4218
    Abstract: Abstract. The evolution of tropospheric ozone from 1850 to 2100 has been studied using data from Phase 6 of the Coupled Model Intercomparison Project (CMIP6). We evaluate long-term changes using coupled atmosphere–ocean chemistry–climate models, focusing on the CMIP Historical and ScenarioMIP ssp370 experiments, for which detailed tropospheric-ozone diagnostics were archived. The model ensemble has been evaluated against a suite of surface, sonde and satellite observations of the past several decades and found to reproduce well the salient spatial, seasonal and decadal variability and trends. The multi-model mean tropospheric-ozone burden increases from 247 ± 36 Tg in 1850 to a mean value of 356 ± 31 Tg for the period 2005–2014, an increase of 44 %. Modelled present-day values agree well with previous determinations (ACCENT: 336 ± 27 Tg; Atmospheric Chemistry and Climate Model Intercomparison Project, ACCMIP: 337 ± 23 Tg; Tropospheric Ozone Assessment Report, TOAR: 340 ± 34 Tg). In the ssp370 experiments, the ozone burden increases to 416 ± 35 Tg by 2100. The ozone budget has been examined over the same period using lumped ozone production (PO3) and loss (LO3) diagnostics. Both ozone production and chemical loss terms increase steadily over the period 1850 to 2100, with net chemical production (PO3-LO3) reaching a maximum around the year 2000. The residual term, which contains contributions from stratosphere–troposphere transport reaches a minimum around the same time before recovering in the 21st century, while dry deposition increases steadily over the period 1850–2100. Differences between the model residual terms are explained in terms of variation in tropopause height and stratospheric ozone burden.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2021
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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