In:
Acta Crystallographica Section E Structure Reports Online, International Union of Crystallography (IUCr), Vol. 70, No. 8 ( 2014-08-15), p. m300-m300
Abstract:
In, K + ·SO 3 – p -C 6 H 4 –N 3 − , the conformation angle of the azido group with respect to the benzene ring is 19.1 (3)°, so that the anion is chiral within the crystal structure. In addition, the crystal structure is also chiral (Sohncke space group). The potassium ion is coordinated by three closer O atoms from three different sulfonyl groups [K...O 2.6486 (17) to 2.7787 (17) Å], three more distant O atoms [K...O 2.959 (2) to 3.206 (2) Å] and three N atoms at 3.073 (2) to 3.268 (2) Å. The anions are packed into layers perpendicular to b , only O and N atoms being at the surface of the layers. The K + ions are located between the layers.
Type of Medium:
Online Resource
ISSN:
1600-5368
DOI:
10.1107/S1600536814015669
DOI:
10.1107/S1600536814015669/hp2068sup1.cif
DOI:
10.1107/S1600536814015669/hp2068sup0.html
DOI:
10.1107/S1600536814015669/hp2068Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2014
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8
Permalink