In:
Chemical Communications, Royal Society of Chemistry (RSC), Vol. 57, No. 78 ( 2021), p. 10095-10098
Abstract:
From conversions of Ar 2 SnH 2 (Ar = Tripp, Dipp; Tripp = 2,4,6-Triisopropylphenyl, Dipp = 2,6-Diisopropylphenyl), and a bismuth( iii ) amide, Bi[N(SiMe 3 ) 2 ] 3 , we isolated the first representatives of mixed, uncharged Bi/Sn clusters, Bi 8 Sn 3 Ar 6 . Along with unprecedented bicyclo[2.2.0]hexanes, (HAr 2 Sn) 2 Sn 2 Bi 4 , these have been characterized by single crystal X-Ray diffraction, heteronuclear NMR, vibrational and UV-Vis spectroscopy. Quantum-chemical calculations were carried out in order to understand bonding within the isolated polyhedral compounds.
Type of Medium:
Online Resource
ISSN:
1359-7345
,
1364-548X
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2021
detail.hit.zdb_id:
215830-9
detail.hit.zdb_id:
1472881-3
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