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  • Trans Tech Publications, Ltd.  (6)
  • Feng, Hui Xia  (6)
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  • Trans Tech Publications, Ltd.  (6)
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  • 1
    Online Resource
    Online Resource
    Trans Tech Publications, Ltd. ; 2011
    In:  Advanced Materials Research Vol. 221 ( 2011-3), p. 211-215
    In: Advanced Materials Research, Trans Tech Publications, Ltd., Vol. 221 ( 2011-3), p. 211-215
    Abstract: Activated montmorillonite(MMT) was modified by toluene diisocyanate(TDI) and TDI-montmorillonite(TDI-MMT) was prepared. The characterization of TDI-MMT was carried out by X-ray diffraction(XRD) and fourier transform infrared spectrometry (FT-IR). The results showed that TDI had been inserted to the interlayer of MMT and the interlayer spacing of MMT increased by 0.26nm. With stannous chloride as catalyst, the biodegradable polylactide acid/TDI-montmorillonite(PLA/TDI-MMT) nanocomposites were synthesized through ring-opening polymerization of lactide in the layer of TDI-MMT by in-situ polymerization. The structure and thermal stability of nanocomposites were investigated by XRD, FT-IR and thermogravimetry (TG). Exfoliated nanocomposites were obtained as shown by XRD results. FT-IR spectra confirmed that TDI-MMT participated in the ring-opening polymerization of lactide. TG analysis indicated the decomposition temperature of nanocomposites rose and the thermal stability was improved contrast to the neat PLA. The effect of the content of TDI-MMT on the molecular weight and thermal stability of nanocomposites was studied. With the increase of the proportion of TDI-MMT, the molecular weight of resultant nanocomposites decreased and the decomposition temperature rose at the range of experiment research.
    Type of Medium: Online Resource
    ISSN: 1662-8985
    URL: Issue
    Language: Unknown
    Publisher: Trans Tech Publications, Ltd.
    Publication Date: 2011
    detail.hit.zdb_id: 2265002-7
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  • 2
    Online Resource
    Online Resource
    Trans Tech Publications, Ltd. ; 2009
    In:  Advanced Materials Research Vol. 87-88 ( 2009-12), p. 422-426
    In: Advanced Materials Research, Trans Tech Publications, Ltd., Vol. 87-88 ( 2009-12), p. 422-426
    Abstract: In this work, the biodegradable poly(lactic acid) (PLA)/organic-montmorillonite (O-MMT) nanocomposites were successfully prepared by the in situ polymerization intercalation process of D,L-lactide with organically-modified montmorillonite which was first treated by Cu cations and second treated by n-hexadecyl trimethylammonium bromide (CTAB) cations. O-MMT was characterized by FT-IR and XRD, the results showed that Cu cations and CTAB cations had been inserted to the interlayer of MMT, and the interlayer spacing of CTAB-Cu-MMT (O-MMT) increased by 1.829nm. The biodegradable PLA/O-MMT nanocomposites were characterized by XRD, SEM, FT-IR, TG, and the results showed that silicate layers were intercalated into the PLA matrix and the biodegradable PLA/O-MMT nanocomposites were of two different types: intercalated nanocomposites and exfoliated nanocomposites. This new nanocomposites frequently exhibited remarkable improvements when compared with the neat PLA matrix. Improvements could include increased heat distortion temperature, an increase in the biodegradability rate of biodegradable polymers.
    Type of Medium: Online Resource
    ISSN: 1662-8985
    URL: Issue
    Language: Unknown
    Publisher: Trans Tech Publications, Ltd.
    Publication Date: 2009
    detail.hit.zdb_id: 2265002-7
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  • 3
    Online Resource
    Online Resource
    Trans Tech Publications, Ltd. ; 2014
    In:  Advanced Materials Research Vol. 1022 ( 2014-8), p. 22-25
    In: Advanced Materials Research, Trans Tech Publications, Ltd., Vol. 1022 ( 2014-8), p. 22-25
    Abstract: In this paper, the preparation of PANI was investigated via in secondary doping in-situ chemical oxidation polymerization. We use NH 2 SO 3 H as dopant, and HP 3 O 4 , H 2 SO 4 or HCl as secondary dopant, respectively. The influencing of products conductivity was discussed about difference secondary dopant with changing concentration. The synthesized polymer composites are characterized by Fourier Transform Infrared Spectroscopy (FTIR) and four probe conductivity apparatus. The results show that in redoping process, the conductivity of PANI was 3.1746 S/cm when the concentration of HCl was 1.0 mol/L. Meanwhile, the thermal stability of PANI prepared with HP 3 O 4 or H 2 SO 4 as secondary dopant was better than HCl as secondary dopant.
    Type of Medium: Online Resource
    ISSN: 1662-8985
    URL: Issue
    Language: Unknown
    Publisher: Trans Tech Publications, Ltd.
    Publication Date: 2014
    detail.hit.zdb_id: 2265002-7
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  • 4
    Online Resource
    Online Resource
    Trans Tech Publications, Ltd. ; 2012
    In:  Advanced Materials Research Vol. 518-523 ( 2012-05-14), p. 473-477
    In: Advanced Materials Research, Trans Tech Publications, Ltd., Vol. 518-523 ( 2012-05-14), p. 473-477
    Abstract: In sequencing batch reactor aerobic granular sludge was cultivated, and the influence of influent C/N ratio to aerobic granular sludge was studied. The results showed that the granulation and the settling ability of the sludge were poor in high C/N, however, low C/N was beneficial to the accumulation of microorganism in reactor and MLSS could reach to as high as 8740 mg/L. Lower C/N ratio would lead to increase of particle size and disintegrate of loose structure and overgrowth on filamentous microbe, these were disadvantage of the stability of the system. It was not obvious that influent C/N ratio affected on the organic removal. The COD removal maintained at 87% after the preliminary form particles were formed in reactor. When C/N ratio was 100:15~100:35, the phosphorus removal efficiency was good. If C/N ratio was too high or too low, the formation of sludge granulation would be affected in the process. The influence of C/N ratio to ammonia nitrogen removal efficiency was obvious. While C/N ratio was 100:10, granular sludge had good simultaneous nitrification and denitrification performance, and the average removal of ammonia nitrogen attained to 91%. But low C/N ratio was able to inhibit the activity of nitrifying bacteria and denitrifying bacteria. At that time, ammonia nitrogen removal rate declined sharply in the system.
    Type of Medium: Online Resource
    ISSN: 1662-8985
    URL: Issue
    Language: Unknown
    Publisher: Trans Tech Publications, Ltd.
    Publication Date: 2012
    detail.hit.zdb_id: 2265002-7
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  • 5
    Online Resource
    Online Resource
    Trans Tech Publications, Ltd. ; 2013
    In:  Key Engineering Materials Vol. 562-565 ( 2013-7), p. 1137-1142
    In: Key Engineering Materials, Trans Tech Publications, Ltd., Vol. 562-565 ( 2013-7), p. 1137-1142
    Abstract: We prepared the polyaniline@polypyrrole (PAn@PPy) conductive composite by a novel method. The struction like Pre-prepared PAn as the core and PPy as the shell for the composite has been prepared by in-situ polymerization. The PAn@PPy conductive composite presents an electrical conductivity of 12.5 S/cm, which is much higher than pure PAn. The synthesized polymer composites are characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM) and Thermogravimetric analysis (TG). The results indicated that PPy successfully grafted on PAn and the heat resistance of nanocomposite is remarkably increased.
    Type of Medium: Online Resource
    ISSN: 1662-9795
    URL: Issue
    Language: Unknown
    Publisher: Trans Tech Publications, Ltd.
    Publication Date: 2013
    detail.hit.zdb_id: 2073306-9
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  • 6
    Online Resource
    Online Resource
    Trans Tech Publications, Ltd. ; 2011
    In:  Advanced Materials Research Vol. 221 ( 2011-3), p. 316-320
    In: Advanced Materials Research, Trans Tech Publications, Ltd., Vol. 221 ( 2011-3), p. 316-320
    Abstract: Polyacrylonitrile-metal-O-montmorillonite nanocomposites were prepared by means of in situ polymerization. The Na-montmorillonite was modified by quaternary ammonium salt after the exchange of its interlayer cations with Ni2+. Infrared spectra and X-ray powder diffraction were employed to characterize the obtained polyacrylonitrile-metal-O-montmorillonite. The results of FTIR show that metal-O-montmorillonite has been concerned with the polymerization of PAN. The result of X-ray powder diffraction shows that the inserting of the acrylonitrile monomer can enlarge the interlayer space of montmorillonite. It is also shown that the polyacrylonitrile-metal-O- montmorillonite nanocomposites have been synthesized. The thermal stability of PAN /MMT is better than that of pure PAN.
    Type of Medium: Online Resource
    ISSN: 1662-8985
    URL: Issue
    Language: Unknown
    Publisher: Trans Tech Publications, Ltd.
    Publication Date: 2011
    detail.hit.zdb_id: 2265002-7
    Location Call Number Limitation Availability
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