In:
Chemistry – A European Journal, Wiley, Vol. 27, No. 68 ( 2021-12-06), p. 17159-17180
Abstract:
NH 3 temperature‐programmed desorption (NH 3 ‐TPD) is frequently used for probing the nature of the active sites in CuSSZ‐13 zeolite for selective catalytic reduction (SCR) of NO x . Herein, we propose an interpretation of NH 3 ‐TPD results, which takes into account the temperature‐induced dynamics of NH 3 interaction with the active centers. It is based on a comprehensive DFT/GGA+D and first‐principles thermodynamic (FPT) modeling of NH 3 adsorption on single Cu 2+ , Cu + , [CuOH] + centers, dimeric [Cu‐O‐Cu] 2+ , [Cu‐O 2 2− ‐Cu] 2 species, segregated CuO nanocrystals and Brønsted acid sites (BAS). Theoretical TPD profiles are compared with the experimental data measured for samples of various Si/Al ratios and distribution of Al within the zeolite framework. Copper reduction, its relocation, followed by the intrazeolite olation/oxolation processes, which are concomitant with NH 3 desorption, were revealed by electron paramagnetic resonance (EPR) and IR. DFT/FPT results show that the peaks in the desorption profiles cannot be assigned univocally to the particular Cu and BAS centers, since the observed low‐, medium‐ and high‐temperature desorption bands have contributions coming from several species, which dynamically change their speciation and redox states during NH 3 ‐TPD experiment. Thus, a rigorous interpretation of the NH 3 ‐TPD profiles of CuSSZ‐13 in terms of the strength and concentration of the active centers of a particular type is problematic. Nonetheless, useful connections for molecular interpretation of TPD profiles can be established between the individual component peaks and the corresponding ensembles of the adsorption centers.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.202102790
Language:
English
Publisher:
Wiley
Publication Date:
2021
detail.hit.zdb_id:
1478547-X
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