In:
Macromolecular Rapid Communications, Wiley, Vol. 30, No. 21 ( 2009-11-02), p. 1852-1856
Abstract:
Novel poly(2‐(3‐sulfo)benzoyl‐1,4‐phenylene)‐ block ‐polynaphthalimide (PSP‐ b ‐PI) copolymers were successfully synthesized by Ni(0)‐catalyzed copolymerization of 2,5‐dichloro‐3′‐sulfo‐benzophenone and dichloro‐terminated naphthalimide oligomer. The membranes exhibited a microphase‐separated structure and good hydrolytic stability at 130 °C. They showed a fairly strong anisotropy of membrane swelling with much smaller in‐plane swelling, but a rather weak anisotropy of proton conductivity. The membranes had a fairly high through‐plane conductivity in water and even under low relative humidity. The PSP‐ b ‐PI copolymer with an IEC of 1.5 meq · g −1 showed high PEFC performance due to the high through‐plane conductivity. magnified image
Type of Medium:
Online Resource
ISSN:
1022-1336
,
1521-3927
DOI:
10.1002/marc.200900351
Language:
English
Publisher:
Wiley
Publication Date:
2009
detail.hit.zdb_id:
1475027-2
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