In:
Advanced Functional Materials, Wiley, Vol. 29, No. 42 ( 2019-10)
Abstract:
Molybdenum disulfide (MoS 2 ) is a promising high‐capacity anode for lithium‐ion batteries. However, the conversion reaction mechanism of MoS 2 (the delithiation pathway in particular) has been controversial, which limits the rational optimization of its electrochemical performance. The main challenge is how to precisely identify the amorphous nanomaterials generated during lithiation/delithiation. Here, the structural evolutions of MoS 2 during lithiation/delithiation are systematically investigated using synchrotron X‐ray absorption spectroscopy at Mo K‐edge and S K‐edge and Raman spectroscopy. It is revealed that amorphous MoS 2 nanograins rather than sulfur as previously suggested, are formed after delithiation, and that the fully lithiated MoS 2 electrode contains additional Mo‐S related phases besides the known Mo and Li 2 S. Density functional theory simulations suggest that the Mo nanoparticles formed during lithiation are very reactive with Li 2 S, thus enabling the regeneration of MoS 2 upon delithiation. These findings deepen the understanding of the lithiation/delithiation mechanism of MoS 2 , which will pave the way for the rational design of advanced MoS 2 ‐based electrodes.
Type of Medium:
Online Resource
ISSN:
1616-301X
,
1616-3028
DOI:
10.1002/adfm.201904843
Language:
English
Publisher:
Wiley
Publication Date:
2019
detail.hit.zdb_id:
2029061-5
detail.hit.zdb_id:
2039420-2
SSG:
11
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