In:
Inorganic Chemistry Frontiers, Royal Society of Chemistry (RSC), Vol. 10, No. 17 ( 2023), p. 5152-5160
Abstract:
Surface regulating the electronic structure and d-band center of electrocatalysts is very much crucial to improving their alkaline hydrogen evolution reaction (HER) performance. Herein, we combined density functional theory (DFT) computations and experimental studies to prepare and study single transition metal-doped Ni 3 N nanosheets combined on Ni foam (M-Ni 3 N, M = V, Cr, Mn, W, Mo, Co and Fe) for ultra-efficient alkaline hydrogen evolution. Physicochemical characterization of as-synthesized M-Ni 3 N demonstrated that the electrons transferred and aggregated on the catalyst surface, which resulted in their unique electronic structure and chemical composition. DFT computations demonstrated that down-shifting of the d-band center weakened the adsorption energy of hydrogen and transition metal doping directly facilitated the adsorption of H 2 O on M sites (desorption of H on Ni sites) at the surface of M-Ni 3 N. As a result, a heterolytic cleavage process of water on M-Ni 3 N nanosheets was formulated, thus drastically boosting the alkaline HER. Specifically, as the best example, the fabricated V-doped Ni 3 N catalyst exhibited remarkable alkaline HER performance with significantly low overpotential of only 15 mV at a current density of 10 mA cm −2 . The strategy exemplified in this work provides a useful way to rational design for highly efficient hydrogen evolution reaction electrocatalysts.
Type of Medium:
Online Resource
ISSN:
2052-1553
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2023
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