In:
Advanced Synthesis & Catalysis, Wiley, Vol. 352, No. 13 ( 2010-09-10), p. 2153-2158
Abstract:
Close to perfect enantioselectivity (up to 98% ee ) is obtained for the formation of amino nitriles using hydrogen cyanide (HCN) as the cyanide source at room temperature for the first time. In an operationally simple process, the catalyst generated from a partially hydrolyzed titanium alkoxide (PHTA) and ( S )‐ N ‐salicyl‐β‐amino alcohol ligand, catalyzes the cyanation of imines in a short reaction time.
Type of Medium:
Online Resource
ISSN:
1615-4150
,
1615-4169
DOI:
10.1002/adsc.v352:13
DOI:
10.1002/adsc.201000462
Language:
English
Publisher:
Wiley
Publication Date:
2010
detail.hit.zdb_id:
2041384-1
detail.hit.zdb_id:
2033084-4
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