In:
Catalysts, MDPI AG, Vol. 13, No. 3 ( 2023-03-08), p. 542-
Abstract:
Heteroatom-doped porous carbon material (H-PCM) was synthesized using Anacardium occidentale (cashew) nut’s skin by a simple pyrolysis route. The resulting H-PCM was thoroughly characterized by various analytical techniques such as field emission scanning electron microscopy (FE-SEM) with energy-dispersive X-ray (EDX) spectroscopy, high-resolution transmittance electron microscopy (HRTEM), X-ray diffraction (XRD), Raman spectroscopy, nitrogen adsorption–desorption isotherms, X-ray photoelectron spectroscopy (XPS), and attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy. The obtained results strongly demonstrated that the synthesized H-PCM exhibited a porous nature, continuous sponge-like and sheet-like smooth morphology, and a moderate degree of graphitization/crystallinity with oxygen-, nitrogen-, and sulfur-containing functionalities in the carbon matrix. After the structural confirmation, as-prepared H-PCM has used a sustainable electrocatalyst for hydrogen evolution reaction (HER) because the metal-free carbonaceous catalysts are one of the most promising candidates. The H-PCM showed excellent HER activities with a lowest Tafel slope of 75 mV dec−1 and durable stability in 0.5 M H2SO4 aqueous solution. Moreover, this work provides a versatile and effective strategy for designing excellent metal-free electrocatalysts from the cheapest biowaste/biomass for large-scale production of hydrogen gas through electrochemical water splitting.
Type of Medium:
Online Resource
ISSN:
2073-4344
DOI:
10.3390/catal13030542
Language:
English
Publisher:
MDPI AG
Publication Date:
2023
detail.hit.zdb_id:
2662126-5
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