In:
Journal of Chemical Research, SAGE Publications, Vol. 2005, No. 9 ( 2005-09), p. 558-560
Abstract:
Primary aryl amines reacted with aryl halides to give the secondary aryl amines by the catalysis of [Pd(dba) 2 /P(t-Bu) 3 ] at 80 °C in toluene. Secondary aryl amines reacted with 1-bromo-pyrene and 9-bromo-phenanthrene and 2,7-dibromo-9H-fluorene to afford the OLED material of aminopyrene derivatives and aminophenanthrene derivatives and diamino-9H-fluorene type by the catalysis of [Pd(OAc) 2 /P(t-Bu) 3 ] at 120 °C in o-xylene. The product structures were established by 1 H NMR, 13 C NMR, 13 C(DEPT), HRMS spectra. Physical properties were examined by UV-vis, PL and DSC spectra.
Type of Medium:
Online Resource
ISSN:
1747-5198
,
2047-6507
DOI:
10.3184/030823405774308961
Language:
English
Publisher:
SAGE Publications
Publication Date:
2005
detail.hit.zdb_id:
3010810-X
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