In:
Dalton Transactions, Royal Society of Chemistry (RSC), Vol. 52, No. 35 ( 2023), p. 12454-12460
Abstract:
A combination of Ga( i ) centers as important building blocks and scaffolds containing N-heterocyclic imines gives new insights into low-valent Ga chemistry. In this study, a mixture of L Dip NLi (L Dip = 1,3-bis(2,6-diisopropylphenyl)-imidazolin-2-ylidene), t BuOK, and Cp*Ga (Cp* = pentamethylcyclopentadienyl) in toluene afforded [L Dip N-Ga] 2 (1) via salt metathesis. X-ray structure analysis of 1 revealed a four-membered Ga 2 N 2 ring, and DFT studies indicated the presence of a lone pair at each Ga center. In addition, compound 1 demonstrated diverse reactivities towards methyl trifluoromethanesulfonate, diphenyl disulfide, 9,10-phenanthrenequinone, and ECl 2 (E = Ge or Sn).
Type of Medium:
Online Resource
ISSN:
1477-9226
,
1477-9234
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2023
detail.hit.zdb_id:
1472887-4
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