In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 637, No. 10 ( 2011-08), p. 1419-1422
Abstract:
Two coordination polymers, namely [Zn(L)Cl] ( 1 ) and [Zn(L) 2 ] ( 2 ) [L = 4‐(pyridin‐4‐ylmethoxy)benzolic acid] were synthesized under hydrothermal conditions and characterized by single‐crystal X‐ray diffraction analyses, powder X‐ray diffraction, and thermogravimetric analysis. Compounds 1 and 2 have a two‐dimensional square‐shaped structure (the dimensions are 15.43 × 15.43 Å for 1 and 12.064 × 15.017 Å for 2 ) with (4 4 · 6 2 ) topology. Moreover, compounds 1 and 2 exhibit a 3D supramolecular structure made up by strong π–π interactions from the adjacent layers. Furthermore, compounds 1 and 2 show good fluorescence properties in the solid state at room temperature.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v637.10
DOI:
10.1002/zaac.201100136
Language:
English
Publisher:
Wiley
Publication Date:
2011
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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