In:
Chemistry – A European Journal, Wiley, Vol. 24, No. 44 ( 2018-08-06), p. 11309-11313
Abstract:
Following the recent discovery of a new family of hybrid ABX 3 perovskites where X=(H 2 POO) − (hypophosphite), this work reports a facile synthesis for mixed X‐site formate perovskites of composition [GUA]Mn(HCOO) 3− x (H 2 POO) x , with two crystallographically distinct, partially ordered intermediate phases with x =0.84 and 1.53, corresponding to ca. 30 and 50 mol % hypophosphite, respectively. These phases are characterised by single‐crystal XRD and solid‐state NMR spectroscopy, and their magnetic properties are reported.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.201803061
Language:
English
Publisher:
Wiley
Publication Date:
2018
detail.hit.zdb_id:
1478547-X
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