In:
International Journal of Chemical Reactor Engineering, Walter de Gruyter GmbH, Vol. 15, No. 1 ( 2017-01-1)
Abstract:
Rh/γ-Al 2 O 3 nanocatalysts with different metal loading were synthesized by two different techniques i. e. microemulsion and microwave irradiated solvothermal technique. Synthesized nanocatalysts were then successfully implemented for the hydrogenation of 4’,4”(5”)-di-tert-butyldibenzo-18-crown-6 ether (DTBuB18C6) at 70 bar, 353–393 K temperature and 5 h. It was observed that 3 wt% nanocatalyst obtained by microemulsion technique exhibited higher catalytic activity and resulted 40 % conversion with high selectivity towards cis-syn-cis di-tert-dicyclohexano-18-crown-6ether (CSC DTBuCH18C6).
Type of Medium:
Online Resource
ISSN:
2194-5748
,
1542-6580
DOI:
10.1515/ijcre-2015-0204
Language:
Unknown
Publisher:
Walter de Gruyter GmbH
Publication Date:
2017
detail.hit.zdb_id:
2112754-2
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