In:
Advanced Materials Research, Trans Tech Publications, Ltd., Vol. 915-916 ( 2014-4), p. 713-716
Abstract:
In this investigation, Schiff bases aluminum complex was synthesized and used as the initiator in the polymerization of D,L-lactide. The aluminum complex was characterized by infrared spectroscopy (IR), and nuclear magnetic resonance spectroscopy (NMR). The influences of different factors, including reaction time, reaction temperature, and the ratio of D, L-lactide/Al 3+ on the synthesis of polylactide were described. The results showed that Schiff bases aluminum complex could be successfully applied in the ring opening polymerization. The optimum condition of the ring opening polymerization of D,L-lactide, which included D,L-lactide/Al 3+ (mol/mol) ratio of 250, reaction temperature of 120 °C, and reaction time of 16 hours.
Type of Medium:
Online Resource
ISSN:
1662-8985
DOI:
10.4028/www.scientific.net/AMR.915-916
DOI:
10.4028/www.scientific.net/AMR.915-916.713
Language:
Unknown
Publisher:
Trans Tech Publications, Ltd.
Publication Date:
2014
detail.hit.zdb_id:
2265002-7
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