In:
Journal of Materials Chemistry C, Royal Society of Chemistry (RSC), Vol. 11, No. 22 ( 2023), p. 7299-7310
Abstract:
Lanthanide ions have attracted great interest owing to their optical and magnetic properties. Single-molecule magnet (SMM) behavior has been a fascinating science for thirty years. Moreover, chiral lanthanide complexes allow the observation of remarkable circularly polarized luminescence (CPL). However, the combination of both SMM and CPL behaviors in a single molecular system is very rare and deserves attention in the design of multifunctional materials. Four chiral one-dimensional coordination compounds involving 1,1′-Bi-2-naphtol (BINOL)-derived bisphosphate ligands and the Yb( iii ) centre were synthesized and characterized by powder and single-crystal X-ray diffraction. All the Yb( iii )-based polymers displayed field-induced SMM behavior with magnetic relaxation occurring by applying Raman processes and near infrared CPL in the solid state.
Type of Medium:
Online Resource
ISSN:
2050-7526
,
2050-7534
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2023
detail.hit.zdb_id:
2702245-6
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