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  • 1
    In: Geophysical Research Letters, American Geophysical Union (AGU), Vol. 49, No. 10 ( 2022-05-28)
    Abstract: Marine biogenic emissions of reactive volatile organic compounds previously thought to be anthropogenic Massive emissions of butenes from the coastal part of the Benguela upwelling system Emissions of butenes may contribute to new particle formation in the marine boundary layer
    Type of Medium: Online Resource
    ISSN: 0094-8276 , 1944-8007
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2022
    detail.hit.zdb_id: 2021599-X
    detail.hit.zdb_id: 7403-2
    SSG: 16,13
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  • 2
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 17, No. 8 ( 2017-04-25), p. 5355-5378
    Abstract: Abstract. The STRAP (Synergie Transdisciplinaire pour Répondre aux Aléas liés aux Panaches volcaniques) campaign was conducted over the entire year of 2015 to investigate the volcanic plumes of Piton de La Fournaise (La Réunion, France). For the first time, measurements at the local (near the vent) and at the regional scales were conducted around the island. The STRAP 2015 campaign has become possible thanks to strong cross-disciplinary collaboration between volcanologists and meteorologists. The main observations during four eruptive periods (85 days) are summarised. They include the estimates of SO2, CO2 and H2O emissions, the altitude of the plume at the vent and over different areas of La Réunion Island, the evolution of the SO2 concentration, the aerosol size distribution and the aerosol extinction profile. A climatology of the volcanic plume dispersion is also reported. Simulations and measurements show that the plumes formed by weak eruptions have a stronger interaction with the surface of the island. Strong SO2 mixing ratio and particle concentrations above 1000 ppb and 50 000 cm−3 respectively are frequently measured over a distance of 20 km from Piton de la Fournaise. The measured aerosol size distribution shows the predominance of small particles in the volcanic plume. Several cases of strong nucleation of sulfuric acid have been observed within the plume and at the distal site of the Maïdo observatory. The STRAP 2015 campaign provides a unique set of multi-disciplinary data that can now be used by modellers to improve the numerical parameterisations of the physical and chemical evolution of the volcanic plumes.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2017
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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  • 3
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 18, No. 16 ( 2018-08-27), p. 12363-12389
    Abstract: Abstract. The complex vertical distribution of aerosols over coastal southern West Africa (SWA) is investigated using airborne observations and numerical simulations. Observations were gathered on 2 July 2016 offshore of Ghana and Togo, during the field phase of the Dynamics-Aerosol-Chemistry-Cloud Interactions in West Africa project. This was the only flight conducted over the ocean during which a downward-looking lidar was operational. The aerosol loading in the lower troposphere includes emissions from coastal cities (Accra, Lomé, Cotonou, and Lagos) as well as biomass burning aerosol and dust associated with long-range transport from central Africa and the Sahara, respectively. Our results indicate that the aerosol distribution on this day is impacted by subsidence associated with zonal and meridional regional-scale overturning circulations associated with the land–sea surface temperature contrast and orography over Ghana and Togo, as typically observed on hot, cloud-free summer days such as 2 July 2016. Furthermore, we show that the zonal circulation evidenced on 2 July is a persistent feature over the Gulf of Guinea during July 2016. Numerical tracer release experiments highlight the dominance of aged emissions from Accra on the observed pollution plume loadings over the ocean, in the area of aircraft operation. The contribution of aged emission from Lomé and Cotonou is also evident above the marine boundary layer. Given the general direction of the monsoon flow, the tracer experiments indicate no contribution from Lagos emissions to the atmospheric composition of the area west of Cotonou, where our airborne observations were gathered. The tracer plume does not extend very far south over the ocean (i.e. less than 100 km from Accra), mostly because emissions are transported northeastward near the surface over land and westward above the marine atmospheric boundary layer. The latter is possible due to interactions between the monsoon flow, complex terrain, and land–sea breeze systems, which support the vertical mixing of the urban pollution. This work sheds light on the complex – and to date undocumented – mechanisms by which coastal shallow circulations can distribute atmospheric pollutants over the densely populated SWA region.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2018
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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  • 4
    In: Geophysical Research Letters, American Geophysical Union (AGU), Vol. 47, No. 19 ( 2020-10-16)
    Abstract: The low single scattering albedo in biomass burning aerosol (BBA) over southern West Africa results from the presence of refractory black carbon The brown carbon contribution to the aerosol absorption is negligible in these well‐aged BBA plumes Accounting for the diversity in black carbon mixing state is needed to accurately estimate BBA optical properties
    Type of Medium: Online Resource
    ISSN: 0094-8276 , 1944-8007
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2020
    detail.hit.zdb_id: 2021599-X
    detail.hit.zdb_id: 7403-2
    SSG: 16,13
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  • 5
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 22, No. 15 ( 2022-08-10), p. 10221-10245
    Abstract: Abstract. Aerosol-aware microphysics parameterisation schemes are increasingly being introduced into numerical weather prediction models, allowing for regional and case-specific parameterisation of cloud condensation nuclei (CCN) and cloud droplet interactions. In this paper, the Thompson aerosol-aware microphysics scheme, within the Weather Research and Forecasting (WRF) model, is used for two fog cases during September 2017 over Namibia. Measurements of CCN and fog microphysics were undertaken during the AErosols, RadiatiOn and CLOuds in southern Africa (AEROCLO-sA) field campaign at Henties Bay on the coast of Namibia during September 2017. A key concept of the microphysics scheme is the conversion of water-friendly aerosols to cloud droplets (hereafter referred to as CCN activation), which could be estimated from the observations. A fog monitor 100 (FM-100) provided cloud droplet size distribution, number concentration (Nt), liquid water content (LWC), and mean volumetric diameter (MVD). These measurements are used to evaluate and parameterise WRF model simulations of Nt, LWC, and MVD. A sensitivity analysis was conducted through variations to the initial CCN concentration, CCN radius, and the minimum updraft speed, which are important factors that influence droplet activation in the microphysics scheme of the model. The first model scenario made use of the default settings with a constant initial CCN number concentration of 300 cm−3 and underestimated the cloud droplet number concentration, while the LWC was in good agreement with the observations. This resulted in droplet size being larger than the observations. Another scenario used modelled data as CCN initial conditions, which were an order of magnitude higher than other scenarios. However, these provided the most realistic values of Nt, LWC, MVD, and droplet size distribution. From this, it was concluded that CCN activation of around 10 % in the simulations is too low, while the observed appears to be higher reaching between 20 % and 80 %, with a mean (median) of 0.55 (0.56) during fog events. To achieve this level of activation in the model, the minimum updraft speed for CCN activation was increased from 0.01 to 0.1 m s−1. This scenario provided Nt, LWC, MVD, and droplet size distribution in the range of the observations, with the added benefit of a realistic initial CCN concentration. These results demonstrate the benefits of a dynamic aerosol-aware scheme when parameterised with observations.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2022
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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  • 6
    In: La Météorologie, Meteo et Climat, Societe Francaise de la Meteorologie et du Climat, Vol. 8, No. 91 ( 2015), p. 29-
    Type of Medium: Online Resource
    ISSN: 0026-1181
    Language: French
    Publisher: Meteo et Climat, Societe Francaise de la Meteorologie et du Climat
    Publication Date: 2015
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  • 7
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 20, No. 8 ( 2020-04-22), p. 4735-4756
    Abstract: Abstract. Southern West Africa (SWA) is an African pollution hotspot but a relatively poorly sampled region of the world. We present an overview of in situ aerosol optical measurements collected over SWA in June and July 2016 as part as of the DACCIWA (Dynamics-Aerosol-Chemistry-Clouds Interactions in West Africa) airborne campaign. The aircraft sampled a wide range of air masses, including anthropogenic pollution plumes emitted from the coastal cities, long-range transported biomass burning plumes from central and southern Africa and dust plumes from the Sahara and Sahel region, as well as mixtures of these plumes. The specific objective of this work is to characterize the regional variability of the vertical distribution of aerosol particles and their spectral optical properties (single scattering albedo: SSA, asymmetry parameter, extinction mass efficiency, scattering Ångström exponent and absorption Ångström exponent: AAE). The first findings indicate that aerosol optical properties in the planetary boundary layer were dominated by a widespread and persistent biomass burning loading from the Southern Hemisphere. Despite a strong increase in aerosol number concentration in air masses downwind of urban conglomerations, spectral SSA were comparable to the background and showed signatures of the absorption characteristics of biomass burning aerosols. In the free troposphere, moderately to strongly absorbing aerosol layers, dominated by either dust or biomass burning particles, occurred occasionally. In aerosol layers dominated by mineral dust particles, SSA varied from 0.81 to 0.92 at 550 nm depending on the variable proportion of anthropogenic pollution particles externally mixed with the dust. For the layers dominated by biomass burning particles, aerosol particles were significantly more light absorbing than those previously measured in other areas (e.g. Amazonia, North America), with SSA ranging from 0.71 to 0.77 at 550 nm. The variability of SSA was mainly controlled by variations in aerosol composition rather than in aerosol size distribution. Correspondingly, values of AAE ranged from 0.9 to 1.1, suggesting that lens-coated black carbon particles were the dominant absorber in the visible range for these biomass burning aerosols. Comparison with the literature shows a consistent picture of increasing absorption enhancement of biomass burning aerosol from emission to remote location and underscores that the evolution of SSA occurred a long time after emission. The results presented here build a fundamental basis of knowledge about the aerosol optical properties observed over SWA during the monsoon season and can be used in climate modelling studies and satellite retrievals. In particular and regarding the very high absorbing properties of biomass burning aerosols over SWA, our findings suggest that considering the effect of internal mixing on absorption properties of black carbon particles in climate models should help better assess the direct and semi-direct radiative effects of biomass burning particles.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2020
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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  • 8
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 19, No. 24 ( 2019-12-16), p. 15217-15234
    Abstract: Abstract. Vast stretches of agricultural land in southern and central Africa are burnt between June and September each year, which releases large quantities of aerosol into the atmosphere. The resulting smoke plumes are carried west over the Atlantic Ocean at altitudes between 2 and 4 km. As only limited observational data in West Africa have existed until now, whether this pollution has an impact at lower altitudes has remained unclear. The Dynamics-aerosol-chemistry-cloud interactions in West Africa (DACCIWA) aircraft campaign took place in southern West Africa during June and July 2016, with the aim of observing gas and aerosol properties in the region in order to assess anthropogenic and other influences on the atmosphere. Results presented here show that a significant mass of aged accumulation mode aerosol was present in the southern West African monsoon layer, over both the ocean and the continent. A median dry aerosol concentration of 6.2 µg m−3 (standard temperature and pressure, STP) was observed over the Atlantic Ocean upwind of the major cities, with an interquartile range from 5.3 to 8.0 µg m−3. This concentration increased to a median of 11.1 µg m−3 (8.6 to 15.7 µg m−3) in the immediate outflow from cities. In the continental air mass away from the cities, the median aerosol loading was 7.5 µg m−3 (5.9 to 10.5 µg m−3). The accumulation mode aerosol population over land displayed similar chemical properties to the upstream population, which implies that upstream aerosol is a significant source of aerosol pollution over the continent. The upstream aerosol is found to have most likely originated from central and southern African biomass burning. This demonstrates that biomass burning plumes are being advected northwards, after being entrained into the monsoon layer over the eastern tropical Atlantic Ocean. It is shown observationally for the first time that they contribute up to 80 % to the regional aerosol loading in the monsoon layer over southern West Africa. Results from the COSMO-ART (Consortium for Small-scale Modeling – Aerosol and Reactive Trace gases) and GEOS-Chem models support this conclusion, showing that observed aerosol concentrations over the northern Atlantic Ocean can only be reproduced when the contribution of transported biomass burning aerosol is taken into account. As a result, the large and growing emissions from the coastal cities are overlaid on an already substantial aerosol background. Simulations using COSMO-ART show that cloud droplet number concentrations can increase by up to 27 % as a result of transported biomass burning aerosol. On a regional scale this renders cloud properties and precipitation less sensitive to future increases in anthropogenic emissions. In addition, such high background loadings will lead to greater pollution exposure for the large and growing population in southern West Africa. These results emphasise the importance of including aerosol from across country borders in the development of air pollution policies and interventions in regions such as West Africa.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2019
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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