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  • Azrague, K.  (3)
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  • 1
    Online-Ressource
    Online-Ressource
    IWA Publishing ; 2009
    In:  Water Supply Vol. 9, No. 6 ( 2009-12-01), p. 653-660
    In: Water Supply, IWA Publishing, Vol. 9, No. 6 ( 2009-12-01), p. 653-660
    Kurzfassung: This paper presents the use of a V-UV/UV/TiO2 reactor (M300 water purifier®) for the removal of sulfamethoxazole and atrazine from natural water. The efficiency of the different processes (photolysis, Vacuum UV (V-UV) and photocatalysis) within the photoreactor was investigated using para-chlorobenzoic acid (pCBA) which is a good probe for hydroxyl radicals. The effect of pH, dissolved organic carbon (DOC) and total inorganic carbon (TIC) was also studied. V-UV was found to be the most efficient process for pCBA degradation within this unit. No photocatalytic degradation was observed. The water quality largely affected the efficiency of the system. Indeed, both DOC and TIC lowered the hydroxyl radical concentration in the system, but DOC did it to a larger extent. Atrazine and sulfamethoxazole, were successfully degraded, and as for pCBA, V-UV was the most efficient process. Sulfamethoxazole displayed a better removal by photocatalysis than atrazine and pCBA. In addition, there was a larger contribution of photolysis during the degradation of sulfamethoxazole than of atrazine. The UV254 nm absorbance of the water affected the photolysis of sulfamethoxazole which has a high molar extinction coefficient and quantum yield at 254 nm, while the DOC is mainly competing with the pollutants for the hydroxyl radicals.
    Materialart: Online-Ressource
    ISSN: 1606-9749 , 1607-0798
    RVK:
    Sprache: Englisch
    Verlag: IWA Publishing
    Publikationsdatum: 2009
    ZDB Id: 2967640-X
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Online-Ressource
    Online-Ressource
    IWA Publishing ; 2007
    In:  Water Science and Technology Vol. 56, No. 10 ( 2007-11-01), p. 101-108
    In: Water Science and Technology, IWA Publishing, Vol. 56, No. 10 ( 2007-11-01), p. 101-108
    Kurzfassung: With the process combination Ozonation-Biofiltration-Membranefiltration (the OBM-process) an average removal of 63% for UV-absorbance (UV254), 79% for color, and 28% for DOC was obtained treating NOM containing surface water. In this paper, focus has been made on the removal of particles after the ozonation and biofiltration treatment steps, using a submerged hollow fiber ultrafiltration membrane reactor. For this purpose the membrane performed adequately. The ultrafiltration step did not have a significant impact on the removal of color, UV254, and DOC. However, the SS and the heterotrophic plate count (HPC) was almost completely removed, and the turbidity was reduced by 65% by the membrane filtration, even at very high fluxes. Fouling occurred during operation, and operational factors of both the ozonation/biofiltration and the membrane reactor were important for controlling this. The experiments at pH 6.5 gave a higher permanent fouling than at pH 8.5, which was caused by the different oxidation pathways and consequently by the change in size and hydrophobicity of the by-products. On the other hand, the reversible fouling was less important at low pH. The mechanical cleaning was efficient, however, it seemed that the air scouring participated to the formation of submicron particles which favored the fouling.
    Materialart: Online-Ressource
    ISSN: 0273-1223 , 1996-9732
    Sprache: Englisch
    Verlag: IWA Publishing
    Publikationsdatum: 2007
    ZDB Id: 764273-8
    ZDB Id: 2024780-1
    SSG: 14
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    Online-Ressource
    Online-Ressource
    IWA Publishing ; 2009
    In:  Water Science and Technology Vol. 59, No. 6 ( 2009-03-01), p. 1209-1217
    In: Water Science and Technology, IWA Publishing, Vol. 59, No. 6 ( 2009-03-01), p. 1209-1217
    Kurzfassung: The catalytic effect of commercially available ceramic Raschig rings versus stainless steel rings (known to be oxidant resistant) at different water qualities, for the decomposition of ozone and the hydroxyl radical formation have been investigated by using an ozone bubble column. Para-chlorobenzoic acid (pCBA) has been used as a model pollutant since it has been reported to be an ideal compound for ozone AOP studies because it displays slow reaction rates with ozone, but rapid oxidation kinetics with the OH radical. While the ozone was quite stable when the stainless steel rings were used as a packing media, the ceramic media enhanced the decomposition of the ozone. Nevertheless, the water quality was found to significantly affect the ozone stability. Indeed, in addition to high pH, both NOM and TIC lowered the ozone concentration in the system. When considering the degradation of pCBA, the ceramic packing rings, as high pH and NOM, increases its rate constant which is correlated to the higher decomposition of ozone and consequently to higher formation of hydroxyl radicals. In contrast, TIC decreased the degradation rate of pCBA even if it decomposes the ozone which is due to its scavenging effect.
    Materialart: Online-Ressource
    ISSN: 0273-1223 , 1996-9732
    Sprache: Englisch
    Verlag: IWA Publishing
    Publikationsdatum: 2009
    ZDB Id: 764273-8
    ZDB Id: 2024780-1
    SSG: 14
    Standort Signatur Einschränkungen Verfügbarkeit
    BibTip Andere fanden auch interessant ...
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