In:
Chemistry – A European Journal, Wiley, Vol. 28, No. 12 ( 2022-02-24)
Abstract:
Thermally induced cycloisomerization reactions of 1,6‐allenynes gives α‐methylene‐γ‐lactams via intramolecular Alder‐ene reactions. The mechanism is supported by computational and deuterium labelling studies. This thermal, non‐radical method enables the discovery of a hitherto unknown route that proceeds via a divergent mechanism distinct from the previous [2+2] cycloisomerization manifold.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.202104022
Language:
English
Publisher:
Wiley
Publication Date:
2022
detail.hit.zdb_id:
1478547-X
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