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  • Almer, Jonathan  (3)
  • Chemistry/Pharmacy  (3)
  • 1
    In: Journal of Materials Research, Springer Science and Business Media LLC, Vol. 37, No. 1 ( 2022-01-14), p. 208-224
    Abstract: High-temperature-ultrafine precipitate strengthened (HT-UPS) steel is a potential structural material for advanced nuclear reactors; however, its irradiation response is not well understood. This research provides insight into irradiation-induced effects, such as precipitate evolution mechanisms and four-dimensional morphological evolution, in HT-UPS steel using synchrotron micro-computed tomography. Identical specimens were characterized pre-irradiation and post-irradiation following neutron exposure up to 0.3 displacements per atom at 600 °C. Irradiation effects were also differentiated from the annealing response of precipitates. Following neutron irradiation, the average Cr 23 C 6 precipitate size reduced, affected by the synergy of nucleation and growth, ballistic dissolution, and inverse coarsening, which was observed at fluences an order of magnitude lower than previously observed. Annealing at 600 °C for 32 h increased the average Cr 23 C 6 precipitate size and decreased the phase fraction, attributed to precipitate coarsening. The precipitate morphology evolution and resultant mechanisms can be utilized to parameterize and validate microstructural models simulating radiation damage or annealing. Graphical abstract
    Type of Medium: Online Resource
    ISSN: 0884-2914 , 2044-5326
    RVK:
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2022
    detail.hit.zdb_id: 54876-5
    detail.hit.zdb_id: 2015297-8
    Location Call Number Limitation Availability
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  • 2
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 2020
    In:  Journal of Materials Research Vol. 35, No. 17 ( 2020-09-14), p. 2300-2310
    In: Journal of Materials Research, Springer Science and Business Media LLC, Vol. 35, No. 17 ( 2020-09-14), p. 2300-2310
    Abstract: Calcium–magnesium–alumino-silicate (CMAS) particulates enter the aero-engine in a sandy environment, melt and infiltrate into 7 wt% yttria-stabilized zirconia (7YSZ) thermal barrier coatings (TBCs), reducing their lifetime. This leads to chemical degradation in 7YSZ accompanied by tetragonal to monoclinic phase transformation upon cooling. In this work, electron-beam physical vapor deposition coatings were infiltrated with a synthetic CMAS. Synchrotron X-ray diffraction measurements show that CMAS infiltration at 1250 °C has about 43% higher monoclinic phase volume fraction (PVF) at the coating surface compared to 1225 °C and remains consistently higher throughout the coating depth. Additionally, the increase in annealing time from 1 to 10 h results in a 31% higher monoclinic phase at the surface. Scanning electron microscopy revealed the presence of globular monoclinic phases corresponding spatially with the above findings. These results resolve the impact of time and temperature on CMAS infiltration kinetics which is important for mitigation.
    Type of Medium: Online Resource
    ISSN: 0884-2914 , 2044-5326
    RVK:
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2020
    detail.hit.zdb_id: 54876-5
    detail.hit.zdb_id: 2015297-8
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 3
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 2015
    In:  Journal of Materials Research Vol. 30, No. 9 ( 2015-05-14), p. 1380-1391
    In: Journal of Materials Research, Springer Science and Business Media LLC, Vol. 30, No. 9 ( 2015-05-14), p. 1380-1391
    Abstract: High performance materials that can withstand radiation, heat, multiaxial stresses, and corrosive environment are necessary for the deployment of advanced nuclear energy systems. Nondestructive in situ experimental techniques utilizing high energy x-rays from synchrotron sources can be an attractive set of tools for engineers and scientists to investigate the structure–processing–property relationship systematically at smaller length scales and help build better material models. In this study, two unique and interconnected experimental techniques, namely, simultaneous small-angle/wide-angle x-ray scattering (SAXS/WAXS) and far-field high-energy diffraction microscopy (FF-HEDM) are presented. The changes in material state as Fe-based alloys are heated to high temperatures or subject to irradiation are examined using these techniques.
    Type of Medium: Online Resource
    ISSN: 0884-2914 , 2044-5326
    RVK:
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2015
    detail.hit.zdb_id: 54876-5
    detail.hit.zdb_id: 2015297-8
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
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