In:
Journal of the American Oil Chemists' Society, Wiley, Vol. 48, No. 6 ( 1971-06), p. 265-270
Abstract:
Catalysts for the ammonolysis of soybean oil are, in order of decreasing overall effectiveness, ammonium acetate, sodium methoxide, 9‐amino‐nonanoic acid, sodium soyate, ammonium nitrate, alanine, sodium acetate and glycerol. At 125 C, a reaction time of 1 hr and a 30:1 mole ratio of ammonia to ester, ammonium acetate achieved ammonolysis in 16%, 61% and 84% conversions at the respective concentrations of 0.0, 0.1 and 1.0 mole per mole ester groups. Conversion was 98% complete in 4 hr with 1.0 mole. The ammonolysis generally exhibited the expected first order kinetics up to about 80% reaction.
Type of Medium:
Online Resource
ISSN:
0003-021X
,
1558-9331
Language:
English
Publisher:
Wiley
Publication Date:
1971
detail.hit.zdb_id:
2041388-9
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