In:
Macromolecular Chemistry and Physics, Wiley, Vol. 219, No. 18 ( 2018-09)
Abstract:
The hybrid copolymerization of vinyl monomers with cyclic esters endows the formed copolymers new features, such as biodegradability and functionality. However, the recently reported hybrid copolymerizations are mainly based on polar vinyl monomers and cyclic esters catalyzed by organocatalysts. The copolymerization of non‐polar vinyl monomers with cyclic esters is still a challenge. In this work, the copolymerization of β‐butyrolactone (β‐BL) with styrene catalyzed by B(C 6 F 5 ) 3 in the absence of coinitiators is reported. The density functional theory studies suggest the formation of zwitterion between β‐BL and B(C 6 F 5 ) 3 . It is found that β‐BL and styrene are concurrently copolymerized through the macro‐zwitterion intermediates. The obtained copolymers are carefully examined by 1 H NMR, 2D 1 H‐ 13 C HMBC, differential scanning calorimetry, thermogravimetric analysis, hydrolysis experiments, as well as Brady's reagents.
Type of Medium:
Online Resource
ISSN:
1022-1352
,
1521-3935
DOI:
10.1002/macp.v219.18
DOI:
10.1002/macp.201800189
Language:
English
Publisher:
Wiley
Publication Date:
2018
detail.hit.zdb_id:
1475026-0
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