In:
Advanced Functional Materials, Wiley, Vol. 33, No. 21 ( 2023-05)
Kurzfassung:
Na 3 V 2 (PO 4 ) 3 is regarded as a promising candidate for sodium ion batteries. Nevertheless, the poor electronic conductivity, low capacities, and unstable structure limit its further investigations. Herein, a new type of Fe/Mn/Co co‐substituted Na 3 V 2 (PO 4 ) 3 with nitrogen‐doped carbon coating (NFMC) by a facile sol‐gel route is synthesized. The introduced elements feature in both crystal bulk and carbon coating layer. Suitable heteroatom substitution activates more effective Na + to participate in electrochemical process and reinforce the structure. An extra high voltage platform at 3.8 V resulting from the multi‐element synergy (Mn 2+ /Mn 3+ /Mn 4+ ; Co 2+ /Co 3+ ; V 4+ /V 5+ ) is stably and reversibly existed in NFMC to supply added capacities, which is investigated by quantum physics calculations. The high flux paths for Na + migration and spin quantum state distribution in NFMC are demonstrated by molar magneton calculation. Significantly, the generated polyatomic coordination environment of MNC (M = Fe/Co/Mn) in carbon layer is first proposed. The most optimized combination structures are obtained from 69 possible structures and demonstrated by X‐ray absorption spectroscopy. The superior electrochemical performance is precisely forecasted by innovative deep learning. Predicted values with high precision are obtained based on a small number of operating data, extremely short development period, and provide real‐time status references for safer use.
Materialart:
Online-Ressource
ISSN:
1616-301X
,
1616-3028
DOI:
10.1002/adfm.202213711
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
2023
ZDB Id:
2029061-5
ZDB Id:
2039420-2
SSG:
11
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