In:
Angewandte Chemie, Wiley, Vol. 128, No. 41 ( 2016-10-04), p. 13004-13008
Abstract:
Conventional polymer additives have a substantial impact on synthetic inorganic chemistry, but critical shortcomings remain; for example, low solubility in organic solvents and potential thermodynamic aggregates. Poly(ionic liquid)s have now been used as efficient additives that enable a high level control of bismuth sulfide crystals with significant size and morphological diversities. The bismuth sulfides exhibit tunable band structure as a result of the quantum size effects. Moreover, poly(ionic liquid)s are able to couple with as‐synthesized bismuth sulfides chemically and endow a modified surface electronic structure, which allows resultant products to possess outstanding electrocatalytic performance for water oxidation, although its commercial counterpart is catalytically inert.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v128.41
DOI:
10.1002/ange.201607221
Language:
English
Publisher:
Wiley
Publication Date:
2016
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