GLORIA

GEOMAR Library Ocean Research Information Access

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • GEOMAR Catalogue / E-Books
  • Articles  (2)
  • Advances in Difference Equations  (1)
  • Zeitschrift für Anorganische und Allgemeine Chemie  (1)
  • 4008
  • 40082
  • 1
    Publication Date: 2015-01-28
    Description: Abstract. The asymmetrical crystal [Na(15C5) 2 ][Na(15C5)] 2 (AsMo 12 O 40 )] · CH 3 CN ( 1 ) was synthesized. Interestingly, the huge α-keggin ion AsMo 12 is distorted by introduction of CH 3 CN molecules and adopts a chiral assembly with space group P 4 . In contrast, the analogous compound AsW 12 co-crystallizes with trace H 2 O molecules. The hydrogen atoms of H 2 O are positionally disordered with 50 % occupation to correlate with AsW 12 in space group P 4/ m . Solid and solution CD spectra indicate that the crystals of 1 are in R configuration. This leads to the conclusion that molybdenum has greater affinity toward organic CH 3 CN, whereas tungsten has greater affinity to inorganic H 2 O. Additionally, AsMo 12 shows greater deformability than AsW 12 . It is suggested that POMo shows a greater potential as chiral material than POW because of the flexibility of Mo. As a highlight, CH 3 CN can function as a general chiral inducer for the innovation of other chiral crystals, if fixed along one dimension.
    Print ISSN: 0044-2313
    Electronic ISSN: 1521-3749
    Topics: Chemistry and Pharmacology
    Published by Wiley-Blackwell
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 2
    Publication Date: 2014-10-22
    Description: In this paper, we extend the deterministic single-group MSIRS epidemic model to a multi-group model, and we also extend the deterministic multi-group framework to a stochastic one and formulate it as a stochastic differential equation. In the deterministic multi-group model, the basic reproduction number R0 is a threshold that completely determines the persistence or extinction of the disease. By using Lyapunov function techniques, we show that if R0〉1, then the disease will prevail, the infective condition persists and the endemic state is asymptotically stable in a feasible region. If R0⩽1, then the infective condition disappears and the disease dies out. For the stochastic version, we perform a detailed analysis on the asymptotic behavior of the stochastic model, which also depends on the value of R0, when R0〉1, we determine the asymptotic stability of the endemic equilibrium by measuring the difference between the solution and the endemic equilibrium of the deterministic model in time-averaged data. Numerical methods are used to illustrate the dynamic behavior of the model and to solve the systems.
    Print ISSN: 1687-1839
    Electronic ISSN: 1687-1847
    Topics: Mathematics
    Published by SpringerOpen
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...