In:
Canadian Journal of Chemistry, Canadian Science Publishing, Vol. 61, No. 2 ( 1983-02-01), p. 269-275
Abstract:
Stereospecific total syntheses of (±)-2-desoxystemodinone, (+)-2-desoxystemodinone, and (±)-stemodinol are described. Also described are the isolation of (+)-2-desoxystemodinone from S. maritima and its characterization. A strategy for the elaboration of the C/D ring systems of the stemodane diterpenoids, stemarin and aphidicolin, from a common 6-hydroxybicyclo[2.2.2]octan-2-one system is delineated and its efficacy is demonstrated by the synthesis of the stemodane diterpenoids and our previous synthesis of stemarin.
Type of Medium:
Online Resource
ISSN:
0008-4042
,
1480-3291
Language:
French
Publisher:
Canadian Science Publishing
Publication Date:
1983
detail.hit.zdb_id:
1482256-8
Permalink