In:
Chemistry – A European Journal, Wiley, Vol. 23, No. 17 ( 2017-03-23), p. 4055-4059
Abstract:
Direct functionalization of terpyridines is an increasingly important topic in the field of dyes and catalysis as well as supramolecular chemistry, but its synthesis and transformation is usually challenging. Herein, a HOMO‐raising strategy is reported for the construction of a super‐stable novel terpyridine chromophores, in which the selective oxidation of terpyridines at its 3‐position was determined successfully to the synthesis of phenol‐functionalization of terpyridines (TPyOHs) bearing a hydrogen bonding group. The corresponding TPyOHs displayed strong aggregation‐induced emission and exhibited highly selective and visual detection of Zn II cation with a record green terpyridine‐based luminophore with nanomolar sensitivity (125 n m ).
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.201605793
Language:
English
Publisher:
Wiley
Publication Date:
2017
detail.hit.zdb_id:
1478547-X
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