In:
Dalton Transactions, Royal Society of Chemistry (RSC), Vol. 50, No. 45 ( 2021), p. 16568-16577
Abstract:
The reactivity of the secondary phosphide KP( i Pr)Ter (1) (Ter = 2,6-bis-(2,4,6-trimethylphenyl)phenyl) toward small molecules is reported. Phosphide 1 displays distinct nucleophilic character and reacts selectively with chalcogens (S 8 , Se x ), heteroallenes (CO 2 , n PrNCS), and an acyl chloride (AdCOCl) to give the corresponding dichalcogenophosphinates (2a, 3), phosphanyl formate (5), thiocarbamoylphosphane (6a), or acylphosphane (7a), respectively. Furthermore the follow-up chemistry of these products was investigated. 2a was converted to a PSPS ligand (2b) which forms a Au( i ) complex (2c) with (Me 2 S)AuCl. Likewise, a gold complex of 7a was prepared. All species were isolated and fully characterized.
Type of Medium:
Online Resource
ISSN:
1477-9226
,
1477-9234
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2021
detail.hit.zdb_id:
1472887-4
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