In:
Mineralogical Magazine, Mineralogical Society, Vol. 84, No. 5 ( 2020-10), p. 785-790
Abstract:
A new mineral species of the pyrochlore supergroup, hydroxyplumbopyrochlore (IMA2018-145), (Pb 1.5 ,□ 0.5 )Nb 2 O 6 (OH), has been discovered in the Jabal Sayid peralkaline granitic complex of the Arabian Shield, Saudi Arabia. It is associated with quartz, microcline, ‘biotite’, rutile, zircon, calcite, rhodochrosite, columbite-(Fe), goethite, thorite, bastnäsite-(Ce), xenotime-(Y), samarskite-(Y), euxenite-(Y), hydropyrochlore and fluornatropyrochlore. Hydroxyplumbopyrochlore usually shows euhedral octahedra, slightly rhombic dodecahedra and cubes or their combination (0.01–0.06 mm). The mineral is pale yellow to pale brown, transparent with white streak, and has adamantine to transparent lustre. It is brittle with conchoidal fracture. No cleavage or parting are observed. It is isotropic and non-fluorescent. The average microhardness is 463.4 kg mm –2 . The calculated density is 6.474 g cm –3 . Hydroxyplumbopyrochlore belongs to the cubic crystal system and exhibits the space group Fd $\bar{3}$ m with unit-cell parameters a = 10.5456(6) Å, V = 1172.8(2) Å 3 and Z = 8. Electron microprobe analysis gave (6-point average composition, wt.%): CaO 0.32, SrO 0.16, FeO 0.17, Ce 2 O 3 0.07, Pr 2 O 3 0.02, PbO 51.69, Nb 2 O 5 40.06, SiO 2 0.05, TiO 2 1.68, Ta 2 O 5 4.74, H 2 O calc 0.95, total 99.90, yielding the empirical formula (Pb 1.34 Ca 0.03 Fe 0.01 Sr 0.01 □ 0.61 ) Σ2 (Nb 1.75 Ti 0.12 Ta 0.12 Si 0.01 ) Σ2 O 6 (OH 0.53 O 0.08 □ 0.39 ) Σ1 , where □ = vacancy . The Raman spectrum of hydroxyplumbopyrochlore contains the characteristic bands of O–H vibrations and no bands for H 2 O vibrations.
Type of Medium:
Online Resource
ISSN:
0026-461X
,
1471-8022
Language:
English
Publisher:
Mineralogical Society
Publication Date:
2020
detail.hit.zdb_id:
2034522-7
SSG:
13
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