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  • Walter de Gruyter GmbH  (3)
  • English  (3)
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  • Walter de Gruyter GmbH  (3)
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  • English  (3)
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  • 1
    In: Nanotechnology Reviews, Walter de Gruyter GmbH, Vol. 10, No. 1 ( 2021-09-27), p. 1318-1328
    Abstract: To meet the requirements of automatic production, a new type of green BAl88Si cored solder was developed. The lap brazing experiments were carried out with copper and aluminum as brazing substrates. The microstructure, phase composition, and corrosion behavior of solder joint interface were studied by field emission scanning electron microscopy, energy dispersive spectroscopy, transmission electron microscopy, electron backscattering diffraction, tensile testing machine, and electrochemical workstation. The results show that the brazing joint of Cu/BAl88Si/Al is metallurgical bonding, and the brazing joint of Cu/BAl88Si/Al is composed of Cu 9 Al 4 , CuAl 2 , a-Al, (CuAl 2 + a-Al + Si) ternary eutectic. In addition, there is no obvious preference for each grain in the brazing joint, and there are S texture {123} 〈 634 〉 , Copper texture {112} 〈 111 〉 , and Brass texture {110} 〈 112 〉 . The interface of Cu 9 Al 4 /CuAl 2 is a non-coherent crystal plane and does not have good lattice matching. The average particle size of CuAl 2 is 11.95 µm and that of Al is 28.3 µm. However, the kernel average misorientation (KAM) value at the brazed joint interface is obviously higher than that at the brazed joint interface copper, so the defect density at the brazed joint interface aluminum is higher than that at the brazed joint interface copper. At the same time, due to poor corrosion resistance at the interface on the aluminum side of the brazed joint, serious corrosion spots and corrosion cracks occur at the same time, which leads to the shear performance of the brazed joint decreasing by about 75% after salt spray test for 240 h.
    Type of Medium: Online Resource
    ISSN: 2191-9097
    Language: English
    Publisher: Walter de Gruyter GmbH
    Publication Date: 2021
    detail.hit.zdb_id: 2646548-6
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  • 2
    Online Resource
    Online Resource
    Walter de Gruyter GmbH ; 2006
    In:  Open Chemistry Vol. 4, No. 4 ( 2006-12-1), p. 732-742
    In: Open Chemistry, Walter de Gruyter GmbH, Vol. 4, No. 4 ( 2006-12-1), p. 732-742
    Abstract: Supermolecular complexes formed by oligophenyleneethynylene derivatives and isophthalic acid were studied using AM1 method to obtain binding energy. Electronic spectra and IR spectra of the complexes were calculated by INDO/CIS and AM1 methods based on AM1 geometries. Results indicated that the dimer could be formed by the monomers via hydrogen bonding because of the negative binding energy. Binding energy of the complexes was affected by electronegativity and steric effects of the substituents. The first UV absorptions and IR frequencies of N-H bonds of the complexes were both red-shifted compared with those of the monomers. The complexes could bind small molecules via hydrogen bonds, resulting in the change in UV absorptions and an increase in IR frequencies of N-H bonds.
    Type of Medium: Online Resource
    ISSN: 2391-5420
    Language: English
    Publisher: Walter de Gruyter GmbH
    Publication Date: 2006
    detail.hit.zdb_id: 2825411-9
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  • 3
    Online Resource
    Online Resource
    Walter de Gruyter GmbH ; 2020
    In:  International Journal of Turbo & Jet-Engines Vol. 37, No. 3 ( 2020-08-27), p. 305-317
    In: International Journal of Turbo & Jet-Engines, Walter de Gruyter GmbH, Vol. 37, No. 3 ( 2020-08-27), p. 305-317
    Abstract: Thermal choke is commonly employed in a fixed geometry RBCC combustor to eliminate the need for physically variable exit geometry. This paper proposed detailed numerical studies based on a two-dimensional integration model to characterize thermal choke behaviors driven by various embedded rocket operations in an RBCC engine at Mach 4 in ramjet mode. The influences of different embedded rocket operations as well as the corresponding secondary fuel injection adjustment on thermal choke generation process, the related thermal throat feature, and the engine performance are analyzed. Operations of embedded rocket bring significant effects on the thermal choke behaviors: (1) the thermal throat feature becomes much more irregular influenced by the rocket plume; (2) the occupancy range in the combustor is significantly lengthened; (3) the asynchrony of the flow in different regions accelerating to sonic speed becomes much more significant; (4) as the rocket throttling ratio decreases, the thermal choke position constantly moves upstream integrally, and the heated flow in the top region that is directly affected by the rocket plume reaches sonic speed more rapidly. Finally, we can conclude that appropriate secondary fuel injection adjustment can provide a higher integration thrust for the RBCC engine with the embedded rocket operating, while the thermal choke is stably controlled, and the increased heat release and combustion pressure are well balanced by the variations of pre-combustion shocks in the inlet isolator.
    Type of Medium: Online Resource
    ISSN: 2191-0332 , 0334-0082
    Language: English
    Publisher: Walter de Gruyter GmbH
    Publication Date: 2020
    detail.hit.zdb_id: 2602427-5
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