In:
Science, American Association for the Advancement of Science (AAAS), Vol. 283, No. 5409 ( 1999-03-19), p. 1900-1902
Abstract:
Studies on the long-term degradation of organic light-emitting devices (OLEDs) based on tris(8-hydroxyquinoline) aluminum (AlQ 3 ), the most widely used electroluminescent molecule, reveal that injection of holes in AlQ 3 is the main cause of device degradation. The transport of holes into AlQ 3 caused a decrease in its fluorescence quantum efficiency, thus showing that cationic AlQ 3 species are unstable and that their degradation products are fluorescence quenchers. These findings explain the success of different approaches to stabilizing OLEDs, such as doping of the hole transport layer, introducing a buffer layer at the hole-injecting contact, and using mixed emitting layers of hole and electron transporting molecules.
Type of Medium:
Online Resource
ISSN:
0036-8075
,
1095-9203
DOI:
10.1126/science.283.5409.1900
Language:
English
Publisher:
American Association for the Advancement of Science (AAAS)
Publication Date:
1999
detail.hit.zdb_id:
128410-1
detail.hit.zdb_id:
2066996-3
detail.hit.zdb_id:
2060783-0
SSG:
11
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