In:
Chemistry – A European Journal, Wiley, Vol. 24, No. 26 ( 2018-05-07), p. 6712-6716
Abstract:
A metastable tellurite, Li 2 Mo 3 TeO 12 , revealing a corrugated layered structure in an extremely strained coordination environment was hydrothermally synthesized in high yield. Li 2 Mo 3 TeO 12 undergoes Li + ‐exchange‐driven facile structural transformation reactions to polyoxometalates. The kinetic data for the transformation reactions at various conditions were successfully obtained by simple lab‐source powder X‐ray diffraction. The investigation suggests that the solid‐state transformation reactions may occur through a series of steps; substitution, decomposition, recombination, and precipitation. This new finding could be utilized in discovering functional metastable materials as well as understanding their phase transition mechanisms.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.201704755
Language:
English
Publisher:
Wiley
Publication Date:
2018
detail.hit.zdb_id:
1478547-X
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