In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 639, No. 5 ( 2013-04), p. 733-738
Abstract:
Three new metal complexes were synthesized by reactions of [bis(2‐amino‐ethyl)‐amino]‐acetic acid (HL) and different metal salts at different pH values. Their structures were characterized by X‐ray crystallography. Interestingly, under acidic conditions, the dinuclear structure {Cu 2 [H(L)] 2 Cl 2 }(ClO 4 ) 2 ( 1 ) was obtained, whereas under alkaline conditions, the complexes {[Cu(L)](ClO 4 )} n ( 2 ) and [Cd(L)Cl] n ( 3 ), which exhibit distinct one‐dimensional (1D) structures, were obtained. The results indicate that the pH value, metal ions, and anions have remarkable influence on the formation and structure of the complexes.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.201200527
Language:
German
Publisher:
Wiley
Publication Date:
2013
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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