In:
Angewandte Chemie, Wiley, Vol. 127, No. 13 ( 2015-03-23), p. 4137-4141
Abstract:
The first example of a practical and direct trifluoromethylthiolation reaction of unactivated aliphatic CH bonds employs a silver‐based reagent. The reaction is operationally simple, scalable, and proceeds under aqueous conditions in air. Furthermore, its broad scope and good functional‐group compatibility were demonstrated by applying this method to the selective trifluoromethylthiolation of natural products and natural‐product derivatives.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v127.13
DOI:
10.1002/ange.201411807
Language:
German
Publisher:
Wiley
Publication Date:
2015
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505872-7
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1479266-7
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