In:
Angewandte Chemie, Wiley, Vol. 127, No. 19 ( 2015-05-04), p. 5733-5737
Abstract:
Highly selective, narcissistic self‐sorting can be achieved in the formation of self‐assembled cages of rare earth metals with multianionic salicylhydrazone ligands. The assembly process is highly sensitive to the length of the ligand and the coordination geometry. Most surprisingly, high‐fidelity sorting is possible between ligands of identical coordination angle and geometry, differing only in a single functional group on the ligand core, which is not involved in the coordination. Supramolecular effects allow discrimination between pendant functions as similar as carbonyl or methylene groups in a complex assembly process.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v127.19
DOI:
10.1002/ange.201500400
Language:
German
Publisher:
Wiley
Publication Date:
2015
detail.hit.zdb_id:
506609-8
detail.hit.zdb_id:
1479266-7
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