In:
Acta Crystallographica Section C Structural Chemistry, International Union of Crystallography (IUCr), Vol. 70, No. 7 ( 2014-07-01), p. 650-653
Abstract:
In the title coordination polymer, [Pb(C 14 H 8 N 2 O 4 )(CH 3 OH) 2 ] n , the asymmetric unit contains half of a Pb II cation, half of a 2,2′-(diazene-1,2-diyl)dibenzoate dianionic ligand (denoted L 2− ) and one methanol ligand. Each Pb II centre is eight-coordinated by six O atoms of chelating/bridging carboxylate groups from four L 2− ligands and two O atoms from two terminal methanol ligands, forming a distorted dodecahedron. The [Pb L 2 (MeOH) 2 ] subunits are interlinked via the sharing of two carboxylate O atoms to form a one-dimensional [Pb L 2 (MeOH) 2 ] n chain. Adjacent chains are further connected by L 2− ligands, giving rise to a two-dimensional layer, and these layers are bridged by L 2− linkers to afford a three-dimensional framework with a 4 12 6 3 topology.
Type of Medium:
Online Resource
ISSN:
2053-2296
DOI:
10.1107/S2053229614012534
DOI:
10.1107/S2053229614012534/yp3071sup1.cif
DOI:
10.1107/S2053229614012534/yp3071Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2014
detail.hit.zdb_id:
2025703-X
Permalink