In:
Acta Crystallographica Section E Structure Reports Online, International Union of Crystallography (IUCr), Vol. 69, No. 2 ( 2013-02-15), p. m119-m120
Abstract:
The asymmetric unit of the title coordination polymer, {[Mn(C 6 Cl 2 O 4 )(C 10 H 8 N 2 )]·2C 2 H 5 OH} n , consists of one Mn II ion, one 2,2′-bipyridine (bpy) ligand, one chloranilate (CA 2− ) ligand and two ethanol solvent molecules. The Mn II ion is octahedrally coordinated by two N atoms of one bpy ligand and four O atoms of two chloranilate ions. The chloranilate ion serves as a bridging ligand between the Mn II ions, leading to an infinite zigzag chain along [101]. π–π stacking interactions [centroid–centroid distance = 4.098 (2) Å] is observed between the pyridine rings of adjacent chains. The ethanol molecules act as accepters as well as donors for O—H...O hydrogen bonds, and form a hydrogen-bonded chain along the a axis. The H atoms of the hydroxy groups of the two independent ethanol molecules are each disordered over two sites with equal occupancies.
Type of Medium:
Online Resource
ISSN:
1600-5368
DOI:
10.1107/S1600536813001438
DOI:
10.1107/S1600536813001438/is5235sup1.cif
DOI:
10.1107/S1600536813001438/is5235sup0.html
DOI:
10.1107/S1600536813001438/is5235Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2013
detail.hit.zdb_id:
2843762-7
detail.hit.zdb_id:
2041947-8
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