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  • The Electrochemical Society  (9)
  • Unknown  (9)
  • 1
    Online Resource
    Online Resource
    The Electrochemical Society ; 2014
    In:  ECS Meeting Abstracts Vol. MA2014-04, No. 4 ( 2014-06-10), p. 745-745
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2014-04, No. 4 ( 2014-06-10), p. 745-745
    Abstract: Volatile, flammable carbonate-based liquid electrolytes, although they show good electrochemical performance suitable for practical use, have posed a critical threat to safeties of lithium-ion batteries. This safety concern becomes more serious in newly-emerging application fields such as (hybrid) electric vehicles and grid scale energy storage systems, which employ large-sized, high-capacity lithium-ion batteries. One promising solution to address the liquid electrolyte-induced safety issues is to replace with nonflammable, thermally-stable electrolytes. Here, we demonstrate a new electrolyte system composed of 1M LiTFSI (lithium bis -trifluoromethanesulphonimide) in sebaconitrile (SBN). The SBN is featured with high boiling temperature (~ 375 o C) and nonflammability, which are expected to enable significant improvements in high-temperature performance of SBN-based electrolytes. Based on the characterization of thermal/electrochemical properties of SBN-based electrolytes, their application to lithium-ion batteries is explored as a function of operating temperature. Notably, the cell incorporating SBN-based electrolytes show stable cycling performance at 80 o C. This advantageous effect of SBN-based electrolytes on thermal stability of cell, in comparison to conventional carbonate-based liquid electrolytes, is discussed by scrutinizing the variation in AC impedance of cells and ionic conductivity of the electrolytes as a function of temperature.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2014
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  • 2
    Online Resource
    Online Resource
    The Electrochemical Society ; 2011
    In:  ECS Meeting Abstracts Vol. MA2011-01, No. 31 ( 2011-03-01), p. 1674-1674
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2011-01, No. 31 ( 2011-03-01), p. 1674-1674
    Abstract: Abstract not Available.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2011
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  • 3
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2005-02, No. 13 ( 2006-02-17), p. 534-534
    Abstract: Abstract not Available.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2006
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  • 4
    Online Resource
    Online Resource
    The Electrochemical Society ; 2014
    In:  ECS Meeting Abstracts Vol. MA2014-02, No. 5 ( 2014-08-05), p. 350-350
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2014-02, No. 5 ( 2014-08-05), p. 350-350
    Abstract: Si-based alloy[1] is one of the most promising anode materials for substituting graphite due to its excellent characteristics such as high gravimetric capacity exceeding 1000mAh/g, high safety, good electrochemical stability and low production cost, etc. Currently, graphite anode material is widely used with water-based SBR binder in commercial Li-Ion Batteries and its electrode capacity is about 350mAh/g. In order to increase the energy density of anode electrode there have been many attempts of blending small (less than 10%) quantity of Si-based anode materials with graphite without changing water-based SBR binder system. In this study, we made Si-alloy/Graphite/Single-walled Carbon nanotubes(SWCNTs) blending electrode and evaluate the electrochemical properties. In case of 8% of Si-alloy / 89% of Graphite / 0% SWCNT / 2% of SBR /1% of CMC electrode, the initial discharge capacity is 387mAh/g, initial the coulombic efficiency is 86.2% and the capacity retention after 50 th cycle is 80.7%. In case of 8% of Si-alloy/89.7% of Graphite/ 0.3% SWCNT/ 2% of SBR /1% of CMC electrode, the initial discharge capacity is 393.5mAh/g, the initial coulombic efficiency is 88.4% and the discharge capacity retention after 50cycle is 99.2%. This improvement in the electrochemical properties of the SWCNT added electrode was mainly attributed to the good electric contact between Si-alloy particles and graphite particles during cycles. In other words, the main cause of initial capacity lose in Si-alloy/Graphite blending electrode is to lose electric contact due to the volume change of Si-alloy. This result gives many hints to improve Si-based anode materials. [1] M. Kim et al. Journal of Electroanalytical Chemistry 687 (2012) 84-88
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2014
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  • 5
    Online Resource
    Online Resource
    The Electrochemical Society ; 2014
    In:  ECS Meeting Abstracts Vol. MA2014-02, No. 5 ( 2014-08-05), p. 346-346
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2014-02, No. 5 ( 2014-08-05), p. 346-346
    Abstract: Various portable electronic devices are wildly used in the world due to the remarkable progress of information technology since 2000. It leads to the increasing demand for rechargeable batteries. As a result, Lithium Ion batteries (LIB) are intensively investigated by many researchers. Currently graphite-based anode materials have widely used. In order to extend to rapidly increasing demand and wider applications as electric vehicles, we have to develop a new anode material. Si-based alloy anode material is one of the strongest candidates because it has many advantageous properties such as high capacity, high safety, good electrochemical stability, and low production cost. M. Kim. et al.[1] has developed a good Si-base alloy anode material and they reported the structural and electrochemical properties[1]. The Si-base alloy is consisted of finely dispersed active silicon crystals and surrounding inactive metal matrix. The main role of inactive-matrix in Si-based alloy is suppressing the volume change and it helps the Si-based alloy maintain good cycle performance. In this study, in order to enhance the cycle performance, we have added Sn metal which has theoretical capacity of 972mAh/g. Si and Sn nanocrystallites embedded in Si-Ti-Fe matrix were developed using arc melting followed by a rapid quenching method which could produce a large scale at one time. To identify the reaction mechanism, the ex-situ XRD, SEM, TEM, analyses were employed. Si and Sn nanocrystallites of approximately 100nm were dispersed in matrix composed of Si2TiFe. Consequently the Si/Sn/Si2TiFe composite showed a good cycle performance with 1000mAh/g over 50 cycles. [1]Journal of electroanalytical Chemistry 687 (2012)84-88
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2014
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  • 6
    In: ECS Transactions, The Electrochemical Society, Vol. 1, No. 5 ( 2006-07-07), p. 211-217
    Abstract: HfO2 films were deposited by atomic layer deposition (ALD) with a new Hf precursor-Hf([N(CH3)(C2H5)]3[OC(CH3)3] ) and O3 as oxidant. The crystallization characteristics of the films were studied using XRD, TEM, AFM, and wet etching test. The results were compared with results from films deposited with Hf [N(CH3)2]4 precursor. The HfO2 films deposited with Hf([N(CH3) (C2H5)] 3[OC(CH3)3]) had an amorphous structure after annealing with a temperature below 800 °C under an N2 atmosphere. This caused a difference in the interfacial layer properties and in the electrical performance.
    Type of Medium: Online Resource
    ISSN: 1938-5862 , 1938-6737
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2006
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  • 7
    In: ECS Transactions, The Electrochemical Society, Vol. 69, No. 8 ( 2015-09-11), p. 101-108
    Abstract: Particle contaminants on EUV mask surface can cause CD error during EUV lithography process. These contaminants should be removed from EUV mask. The critical size of defect which can cause 10 % CD error is about 23~38 nm with various materials. Among them, critical defect size of SiO 2 is about 30 nm. To remove this 30 nm fine silica particle, megasonic cleaning was adapted with various megasonic frequencies and with various cleaning solutions such as dilute alkali solution and gas dissolved water. At high megasonic frequency (2 MHz), though bubble cavitation effect is decreased, cavitation threshold value is higher even with the addition of gases into cleaning solution. As a result, higher particle removal efficiency of 30 nm silica particles and lower damages on PR pattern is achieved at 2 MHz megasonic cleaning in a cleaning solution of H 2 gas and dilute NH 4 OH as compared with 1 MHz megasonic cleaning.
    Type of Medium: Online Resource
    ISSN: 1938-5862 , 1938-6737
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2015
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  • 8
    Online Resource
    Online Resource
    The Electrochemical Society ; 2011
    In:  ECS Meeting Abstracts Vol. MA2011-01, No. 19 ( 2011-03-01), p. 1257-1257
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2011-01, No. 19 ( 2011-03-01), p. 1257-1257
    Abstract: Abstract not Available.
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2011
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  • 9
    In: ECS Meeting Abstracts, The Electrochemical Society, Vol. MA2015-02, No. 27 ( 2015-07-07), p. 1021-1021
    Abstract: Extreme ultraviolet lithography (EUVL) is the most promising lithography technique for the 22 nm half-pitch and beyond. The EUV patterned masks work in a reflective mode and it has 40 to 50 pairs of MoSi multilayer to reflect EUV radiation. This multilayer is capped by a 2.5 nm Ru thin film to protect the MoSi multilayer. Since EUV mask does not have a pellicle which protects mask surface from the contaminants. Therefore, EUV mask is more vulnerable to particle contamination during lithography processing which is a major yield loss in device fabrication. No study has been reported on the effect of particle size on CD variation if they exist on EUV mask. The critical defect size, which can cause 10 % CD error, has to be removed from the mask surface. When the defect is located between line and space patterns on the mask, the reflectivity will be reduced due to defect absorption. Simulation predicted that 30 nm sized silica particles can cause 10 % CD error on 16 nm line and space pattern. Thus, these contaminant particles have to be removed from EUV mask surface for preventing CD variation. In order to evaluate the 30 nm sized silica particle removal test, we adopted 30 nm standard spherical silica particles. Actually, it is a challenge to evaluate 30 nm particles removal test without inspection tools. So, we used atomic micro scope (AFM) for the evaluation of these particles. The silica particles were intentionally deposited on Ru surface using spinning method. Cleaning test was performed with twin type megasnoic. 30 nm silica particles removal efficiency was drastically decreased as compared with 137 nm silica particles at 1 MHz megasonic cleaning. Because the megasonic cleaning force was reduced to ultra-fine particles due to boundary layer thickness. Therefore, higher megasonic cleaning force is required to remove ultra-fine particles to overcome boundary layer thickness. It is well known that the large cleaning force is induced, not only particle removal efficiency but also pattern damage will be increased. Thus, megasonic cleaning process without causing pattern damage has to be optimized. In this study, we shall discuss the effect of megasonic frequency on the removal of ultra-fine particles and pattern damage. Also, gas dissolved water and dilute alkali cleaning solution are adopted to high frequency megasonic cleaning process to achieve ultra-fine particles removal without pattern damage effectively. Figure 1
    Type of Medium: Online Resource
    ISSN: 2151-2043
    Language: Unknown
    Publisher: The Electrochemical Society
    Publication Date: 2015
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